HIGH-RESISTANT HOT DIP GALVANIZED STEEL SHEET, HIGH-RESISTANT HOT DIP GALVANIZED STEEL SHEET AND MET

专利摘要:
abstract there is provided a high-strength hot-dip galvanized sheet and the like excellent in mechanical cutting property, which are capable of obtaining high ductility while ensuring high strength with maximum tensile strength of 900 mpa or more. hot-dip galvanized steel sheet has a sheet thickness of 0.6 to 5.0 mm and has a plating layer on a surface of a steel sheet with component compositions being set in appropriate ranges, in which the steel sheet structure contains a 40 to 90% ferrite phase and 3% or more retained austenite phase by volume fraction. in the retained austenite phase, a solid solution carbon is 0.70 to 1.00%, an average grain diameter is 2.0 µm or less, an average distance between grains is 0.1 to 5.0 µm, a thickness of a decarburized layer in a steel sheet surface layer portion is 0.01 to 10.0 µm, an average grain diameter of oxides contained in the steel sheet surface layer portion is 30 to 120 nm and an average density thereof is 1.0 × 1012 oxides / m2 or more, and moreover, a work hardening coefficient (n value) during a 3 to 7% plastic deformation is 0.080 or more on average. ___________________________________________________________________________ translation of the abstract summary patent of the invention: "High strength hot dip galvanized steel sheet and high strength hot dip galvanized steel sheet, excellent in mechanical cutting property and method for its production". An excellent hot-dip galvanized sheet steel is provided in mechanical cutting property which is capable of high ductility while ensuring high strength with a maximum tensile strength of 900 mpa or more. the high strength hot dip galvanized steel plate has a thickness of 0.6 to 5.0 mm and has a coating layer on the steel plate surface with component compositions being adjusted in suitable ranges in which the structure steel plate contains 40 to 90% of a ferrite phase and 3% or more of a retained austenite phase, the amount of carbon in solid solution is 0.70 to 1.00%, the average grain diameter is 2.0 µm or less, the average grain distance is 0.01 to 5.0 µm, the thickness of the decarburized layer in the surface layer portion of the steel plate is 0.01 to 10.0 µm, the average grain diameter of the oxides contained in the surface layer portion of the steel sheet is 30 to 120 nm and their average density is 1.0 × 1012 oxides / m2 or more, and in addition the work hardening coefficient (n value) during A plastic deformation of 3 to 7% is 0.080 or more on average.
公开号:BR112014007545B1
申请号:R112014007545-0
申请日:2012-09-28
公开日:2019-05-14
发明作者:Hiroyuki Kawata；Naoki Maruyama；Akinobu Murasato；Akinobu Minami；Takeshi Yasui；Takuya Kuwayama；Hiroyuki Ban；Kaoru Hiramatsu
申请人:Nippon Steel & Sumitomo Metal Corporation；
IPC主号:

专利说明:

Invention Patent Descriptive Report for HIGH-RESISTANCE HOT-DIP GALVANIZED STEEL PLATE, HIGH-RESISTANCE HOT-GALVANIZED STEEL PLATE AND METHOD FOR THE PRODUCTION OF THE SAME.
TECHNICAL FIELD [001] The present invention relates to a high strength hot dip galvanized steel sheet and a high strength hot dip galvanized alloy steel sheet excellent in mechanical cutting properties, and to a method for its production.
BACKGROUND OF THE TECHNIQUE [002] In recent years the demand for increasing the strength of steel plates used in automobiles or the like has increased, and high-strength steel plates with maximum tensile strength of 900 MPa the most are beginning to be used in with a view to improving collision safety, etc.
[003] Generally, since the forming capacity of steel sheets deteriorates with increasing strength, the development of high strength steel sheets whose forming capacity does not deteriorate is in progress, that is, it has good forming capacity even when your resistance is increased. For example, in the steel sheets described in Patent Literature 1, the structure of the steel sheet consists of ferrite and martensite in order to guarantee high elongation even though it has high strength. In addition, a steel sheet structure consisting of ferrite, retained austenite and bainite described in Patent Literature 2 achieves an even greater ductility by using the plasticity induced by the transformation of the retained austenite. In addition, steel sheets as described in Patent Literature 1, 2 are excellent in capacity
Petition 870180067961, of 08/06/2018, p. 9/17
2/112 of energy absorption in the collision, and so are used in many elements as structural elements of automobiles.
[004] On the other hand, in a conventional high-strength steel plate, in addition to the problems described above in forming, the deterioration of equipment that processes these steels has become a problem that accompanies the increased strength of these steels. For example, in edge trimming or punching, as high strength steel sheets are processed, problems are arising such as abrasion and breakage of cutting blades and punching tools, and the reduction of tool life is becoming a problem. In addition, when these jobs are performed, the cutting and punching loads are also high, and therefore it is also inevitable to increase the capacity of the equipment.
[005] The cutting process during the cutting and punching process can be divided into three processes: a process of plastic deformation of a steel sheet, a process of fracture formation in a contact position between the scissors or the puncher and the steel sheet or in a contact position between the mold and the steel sheet and, in addition, a process of propagation and connection of these fractures. The plastic deformation and fracture propagation processes as described above fall under a ductile fracture at room temperature and a normal processing (stress) rate, and thus the energy required for the fracture to propagate increases as the strength increases. As a result, the increase in the cutting load that accompanies the high strength has become inevitable.
[006] As steel sheets with improved cutting properties and machining capacity during machining as described above, for example, the steel sheets described in Patent Literature 3, 4 are known. In the steel sheets described in Literatu
3/112 ras of Patent 3, 4, the machining capacity during machining is improved by adding predetermined amounts of Pb, S, Al and dispersing the sulfide oxides based on MnS and / or AI ₂ O ₃ in the steel. According to patent literature 3, 4, machining capacity is improved by dispersing inclusions with poor ductility such as MnS and AI ₂ O ₃ in steel, and allowing these inclusions to break during cutting work. However, since the steel sheets of Patent Literature 3, 4 include a large amount of inclusions (MnS-based sulphides, AI ₂ O ₃ ) throughout the steel, they are inferior in forming capacity which is essential for steel sheets for automobiles represented by forming by pressing and expansion of bore, and there was a problem that they are difficult to be applied to elements that must be formed by pressing. In addition, there is another problem, since the addition of Pb is undesirable also in view of environmental problems.
[007] Meanwhile, Patent Literature 5 describes a steel sheet in which oxides are dispersed only in one surface layer of the steel sheet. The technology described in Patent Literature 5 is such that, by adding Si or Al to the steel and performing the high temperature rolling during hot rolling or performing an additional treatment on a hot rolled steel plate, Si oxides and / or Mn are formed in the surface layer of the steel sheet, thus improving the workability for cutting, punching, etc.
[008] However, in the reaction series as described in Patent Literature 5, the oxides that facilitate the formation of fractures are dispersed by carrying out an additional heat treatment in one step of the hot rolling, and thus the formation of fractures and also facilitated in the process of executing a large plastic deformation such as cold rolling, where there is the possibility of induction
4/112 of fracture in the plate. In addition, when a large amount of oxides that allows the improvement of the machine's working capacity is formed, there is the problem that a fracture initiated in an oxide is formed during cold rolling together with more difficult work, or an oxide peels and gets stuck between the steel sheet and the cylinder during rolling, thus causing a defect in the surface of the steel sheet. Thus, Patent Literature 5 is not a structure designed to improve the mechanical cutting property during cutting.
[009] In addition, Patent Literature 6 proposes a high-strength cold-rolled steel sheet containing oxides containing Si with a distribution of 2 χ 10 ⁶ (oxides / mm ² ) or more in each or both between the edges of crystal grains of 4 pm or less from a surface layer of a steel plate or inside the crystal grains in a surface layer of a steel plate having steel components containing, in mass%, C : 0.07 to 0.25%, Si: 0.3 to 2.50%, Mn: 1.5 to 3.0%, Ti: 0.005 to 0.07%, B: 0.0001 to 0.01 %, P: 0.001 to 0.03%, S: 0.0001 to 0.01%, Al: 0.60% or less, N: 0.0005 to 0.0100%, O: 0.0005 to 0.007% , and having a steel plate structure consisting mainly of ferrite and martensite. In the high-strength cold-rolled steel sheet described in Patent Literature 6, the maximum tensile strength of 900 MPa is guaranteed, and is considered to have excellent mechanical cutting properties. However, the high-strength cold-rolled steel sheet described in Patent Literature 6 has insufficient ductility, and there is the problem that it is difficult to form an element with a complicated shape. LIST OF QUOTES
PATENT LITERATURE
Patent Literature 1: Patent Publication Open to Japanese Public Inspection No. 57-143435
5/112
Patent Literature 2: Japanese Public Inspection Publication No. 01-230715
Patent Literature 3: Japanese Public Inspection Publication No. 59-205453
Patent Literature 4: Publication of
Patent open to
Patent open to
Japanese public inspection open patent n ° 62-23970
Patent Literature 5: Japanese Patent No. 3870891
Patent Literature 6: Patent Publication Open to Japanese Public Inspection No. 2011-111673
SUMMARY OF THE INVENTION
TECHNICAL PROBLEM [0010] The present invention is made in view of the above problems, and its objective is to provide a high strength hot dip galvanized steel sheet and a high strength bonded hot dip galvanized steel sheet excellent in property mechanical cutting, capable of obtaining high ductility while guaranteeing high strength with maximum tensile strength of 900
MPa or more, and a method for its production.
SOLUTION TO THE PROBLEM [0011] The present inventors conducted intensive studies to solve the above problems. As a result, the inventors found that properly adjusting steel components, rolling conditions and annealing conditions after rolling, etc., while controlling the ratio of the austenite phase retained in a steel sheet structure is a predetermined ratio or greater, the amount of solid carbon solution contained in the retained austenite phase, the average grain diameter, and the average distance between grains can be limited to a predetermined range and, in addition, the thickness of a decarburized layer on the surface of the steel plate, the average diameter and grain, and the average density of the oxides can be
6/112 limited to a predetermined range. Thus, the inventors found that in a high-strength hot-dip galvanized steel sheet, by properly adjusting the austenite phase retained in the steel sheet structure, excellent ductility and mechanical cutting property can be obtained while ensuring a strength maximum tensile strength of 900 MPa or more and, furthermore, that by properly adjusting the thickness of the decarburized layer in the portion of the surface layer of the steel sheet and the sizes of the oxides, the adhesion capacity of the coating layer increases, completing thus the present invention.
[0012] Specifically the essence of the present invention is as follows.
[1] A hot-dip galvanized steel sheet of high strength excellent in mechanical cutting property, having a thickness of 0.6 to 5.0 mm and having a coating layer on a surface of the steel sheet containing, in Mass%, C: 0.075 to 0.400%, Si: 0.01 to 2.00%, Mn: 0.80 to 3.50%, P: 0.0001 to 0.100%, S: 0.0001 to 0, 0100%, Al: 0.001 to 2.00%, N: 0.0001 to 0.0100%, and O: 0.0001 to 0.0100% with the balance being made up of iron and the inevitable impurities, where: in a range of 1/8 of thickness to 3/8 of thickness with 1/4 of thickness being the center from the surface of the steel plate, the structure of the steel plate contains at least 40 to 90% of ferrite phase and 3% or more of austenite phase retained in fraction of volume; in the retained austenite phase, the amount of solid carbon solution in the phase is 0.70 to 1.00%, the average grain diameter is 2.0 pm or less, and the average distance between grains is 0.1 to 5, 0 pm; the thickness of a decarburized layer in a portion of the surface layer of the steel plate is 0.01 to 10.0 pm, the average grain diameter of the oxides contained in the portion of the surface layer of the steel plate is 30 to 120 nm and its average density is 1.0 χ 10 ¹²
7/112 oxides / m ² or more; and, in addition, the hardening coefficient at work (n value) during a plastic deformation of 3 to 7% is 0.00 or more on average.
[2] The high-resistance hot-dip galvanized steel sheet excellent in mechanical cutting properties as per item [1] above, also containing, in mass%, one or more elements between Ti: 0.001 to 0.150%, Nb : 0.001 to 0.100%, and V: 0.001 to 0.300%.
[3] The high-resistance hot-dip galvanized steel sheet excellent in mechanical cutting properties according to item [1] or [2] above, also containing, in mass%, one or more elements between Cr: 0, 01 to 2.00%, Ni: 0.01 to 2.00%, Cu: 0.01 to 2.00%, Mo: 0.01 to 2.00%, B: 0.0001 to 0.0100% , and W: 0.01 to 2.00%.
[4] The hot-dip galvanized steel sheet of high strength excellent in mechanical cutting properties according to items [1] to [3] also containing, in mass%, 0.0001 to 0.0100% in total one or more elements between Ca, Ce, Mg, Zr, La, and REM.
[5] The high-strength hot-dip galvanized steel sheet, excellent in mechanical cutting properties, formed by bonding the coating layer of the high-strength hot-dip galvanized steel sheet according to any of the items [1] to [4] above.
[6] A method of producing a hot-dip galvanized steel sheet of excellent high strength in mechanical cutting property, the method including: a laminating step of heating up to 1180Ό or more a plate having a chemical composition, in% mass, C: 0.075 to 0.400%, Si: 0.01 to 2.00%, Mn: 0.80 to 3.50%, P: 0.0001 to 0.100%, S: 0.0001 to 0.0100 %, Al: 0.001 to 2.00%, N: 0.0001 to 0.0100%, and O: 0.0001 to 0.0100% with the balance
8/112 being iron and the inevitable impurities, directly or after being cooled once and performing the hot lamination in which the lamination finish temperature is 850 to 950Ό, then cool quickly to 500 to 650Ό at an average cooling rate 10C / s or more, and then wind up in a coil and cool slowly to 400Ό taking 1 hour or more; a cold rolling step of carrying out cold rolling so that the total reduction ratio is 30 to 75% after blasting subsequent to the hot rolling step; an annealing step of heating the steel sheet after the cold rolling step to 750Ό or more with the average heating rate between 600 and 750Ό being 20Ό / or less, and then cooling with the average cooling rate between 750 and 650Ό with 1.0 to Ιδ, ΟΌ / ε and cool with the average cooling rate from 650Ό with 3.0O / s or more, and run, while remaining for 20 to 1000 seconds in the temperature range of 300 to 470Ό and while the tension of 5 to 100 MPa is applied in this temperature range, one or more times the bending with a bending radius of 800 mm or less; a coating step of performing hot dip galvanizing on the steel sheet surfaces to form a coating layer by immersing the steel sheet after the annealing step in a galvanizing bath under the coating bath temperature conditions: 450 to 470Ό, temperature of the steel plate when entering the coating bath: 430 to 490Ό, and effective amount of Al in the coating bath: 0.01 to 0.18% by weight; and the cooling step of cooling at an average cooling rate of 0.5Ό / ε or more to 150O / S or less after the coating step, where the annealing step is such that the preheat zone under the condition of a air ratio: 0.7 to 1.2 in a mixed air gas and a combustible gas used in a preheat burner, the air ratio being the ratio of the volume of air contained
9/112 in the mixed gas in a volume unit and the volume of air logically necessary for the complete combustion of the combustible gas contained in the mixed gas in the volume unit, oxides are generated in a portion of the surface of the steel plate through the passage of the plate while heating to a steel plate temperature of 400 to 800Ό, then the oxides generated in the preheat zone are reduced by heating to 750Ό or more in a reduction zone with a partial pressure ratio P (H ₂ O) / P (H ₂ ) between water vapor (H ₂ O) and hydrogen (H ₂ ): 0.0001 to 2.0, and then cooling is performed.
[7] A method of producing a hot-dip galvanized steel sheet of high strength excellent in mechanical cutting property, the method including, after the hot rolling step, the cold rolling step, the annealing, and the coating step are performed by the method as per item [6] above, perform a bonding treatment in a coating layer formed in the coating step at temperatures from 470 to 620Ό.
[0013] It is noted that the hardening coefficient at work (n value) defined in the present invention is a characteristic value to be the reference of the stamping property (ductility), and refers to an index n when an approximation of the relationship between pressure σ and stress ε in a plastic region equal to or greater than the yield point. An approximate expression at this point is, although depending on the material, for example, the simplest law of hardening to the umpteenth power, σ = Οε ^η , or in addition, an optimal Swift or similar expression for iron material can be used. The higher the n value, the greater the elongation until local contraction occurs, thereby improving ductility. On the other hand, there is the characteristic that the lower the n value, but the cutting property
10/112 mechanic improves.
ADVANTAGE EFFECTS OF THE INVENTION [0014] The high-strength hot-dip galvanized steel sheet and the high-strength hot-dip galvanized steel sheet excellent in mechanical cutting property of the present invention employs a structure in which the components of the steel, the structure of the steel plate, the thickness of the decarburized layer and the size, etc., of the oxides on the surface portion of the steel plate, etc., are defined for suitable ranges as described above. That is, by containing an adequate amount or more of the austenite phase retained in the steel plate structure, the work hardening capacity is increased, so that the strength and ductility of the steel plate can be improved, and in the meantime increasing it if the density by limiting the amount of carbon in the solid solution in the retained austenite phase and suppressing the average grain diameter, the mechanical cutting property when processing the steel sheet (punching work capacity) improves. In addition, by limiting the thickness of the decarburized layer and the average grain diameter and the average density of the oxides in the surface layer portion of the steel sheet, the adhesion capacity of the coating layer improves. Therefore, while guaranteeing the maximum tensile strength of 900 MPa or more, the high-strength hot-dip galvanized steel sheet and the high-strength hot-dip galvanized steel sheet capable of obtaining excellent ductility and cutting properties mechanics can be performed.
[0015] In addition, the method of producing the high strength hot dip galvanized steel sheet and the high strength hot dip galvanized steel sheet of the present invention employs a method that adjusts the steel components to
11/112 a suitable range, and limits the conditions of hot rolling, cold rolling and annealing after rolling to predetermined ranges. Thus, the ratio of the austenite phase retained in the steel plate structure can be controlled to a predetermined ratio or more, and the average grain diameter and the average distance between grains can be limited to a predetermined range while limiting the amount of carbon in the solid solution contained in the retained austenite phase, and thus it is possible to improve the strength and ductility, as well as the mechanical cutting property of the steel sheet. In addition, since the thickness of the decarburized layer, the average grain diameter and the average density of the oxides in the surface layer portion of the steel sheet can be limited to a predetermined range, it is possible to improve the adhesion capacity of the steel sheet. coating layer. Therefore, while guaranteeing the maximum tensile strength of 900 MPa or more as described above, it is possible to produce the high strength hot dip galvanized steel sheet and the high strength bonded hot dip galvanized steel sheet capable of obtaining excellent ductility and mechanical cutting property.
[0016] Therefore, applying the high-strength hot-dip galvanized steel sheet and the high-strength hot-dip galvanized steel sheet excellent in mechanical cutting property, and its production method of the present invention in the automotive field in particular, merits such as improved safety along with increased strength of the vehicle's chassis, improved work capacity for processing an element, etc., can be sufficiently leveraged, and their social contributions are immeasurable.
DESCRIPTION OF SETTINGS [0017] Hereafter, a high-strength hot-dip galvanized steel sheet and a galvanized steel sheet will be described
12/112 using high-strength hot-dip alloy excellent mechanical cutting properties, and a method of producing the same as configurations of the present invention. Note that this configuration is for detailed explanations to allow a better understanding of the concepts of high-strength hot-dip galvanized steel sheet and of high-strength hot-dip galvanized steel sheet excellent in mechanical cutting properties, and its method of production of the present invention, and thus does not limit the invention unless specifically specified. Note that in the description below,% denotes% by mass unless specifically specified.
[0018] High strength hot dip galvanized steel sheet [0019] The high strength hot dip galvanized steel sheet excellent in mechanical cutting properties of this configuration (which can now be abbreviated simply for galvanized steel sheet by high-strength hot-dip) is formed to have a coating layer on the surface of the steel sheet containing, in mass%, C: 0.075 to 0.400%, Si: 0.01 to 2.00%, Mn: 0, 80 to 3.50%, P: 0.0001 to 0.100%, S: 0.0001 to 0.0100%, Al: 0.001 to 2.00%, N: 0.0001 to 0.0100%, and O: 0.0001 to 0.100% with the balance being made up of iron and the inevitable impurities. In addition, the high-strength hot-dip galvanized steel sheet of this configuration has a thickness of 0.6 to 5.0 mm. In addition, in the high-strength hot-dip galvanized steel sheet of this configuration, in a range of 1/8 of the thickness to 3/8 of the thickness with 1/4 of the thickness of the steel sheet being the center from the surface of the steel plate, the structure of the steel plate contains at least 40 to 90% of a ferrite phase and 3% or more of an austenite phase retained in fraction of volume, and in that phase austenite reti
13/112 da, the amount of carbon in the solid solution the phase is 0.70 to 1.00%, the average grain diameter is 2.0 pm or less, and the average distance between grains is 0.1 to 5, 0 pm. In addition, in the high-strength hot-dip galvanized steel sheet of this configuration, the thickness of a decarburized layer in the surface layer portion of the steel sheet is 0.01 to 10.0 pm, the average diameter of the oxide contained the portion of the surface layer of the steel plate is 30 to 120 nm, and its average density is 1.0 χ 10 ¹² oxides / m ² or more. So. in high-strength hot-dip galvanized steel sheet of this configuration, the hardening coefficient at work (n value) during plastic deformation of 3 to 7% is 0.080 or more on average.
[0020] Here, the range of 1/8 of the thickness to 3/8 of the thickness with 1/4 of the thickness of the plate from the surface of the plate being the center means the range of 1/8 of the thickness with 1/4 of the plate thickness from the surface of the steel plate being the center to 3/8 of the thickness with 1/4 of the thickness of the plate from the surface of the steel plate being the center. In addition, the focus on the structure of this strip is because the structure of this strip can be considered as representative of the entire steel sheet structure excluding the decarburized layer of the surface layer portion of the steel sheet. That is, when there is a steel plate structure as described above in the range of 1/8 of the thickness to 3/8 of the thickness, it can be judged that the entire steel plate excluding the decarburized layer of the surface portion of the steel plate is the structure as described above.
[0021] The present inventors and others conducted intense studies to realize a high mechanical cutting property while guaranteeing excellent ductility in a high-strength hot-dip galvanized steel sheet with maximum resistance to traction
14/112 tion of 900 MPa or more. As a result, the inventors found that, initially limiting the steel components to a suitable range and making the rolling conditions and the annealing conditions after rolling are in suitable ranges that will be described later, the reason for the phase austenite retained in the steel sheet structure can be controlled for a predetermined ratio or more, and the average diameter and grain and the average distance between grains can be limited to predetermined ranges while limiting the amount of carbon in the solid solution contained in the austenite phase retained. It has been found that, through this, both the ductility and the mechanical cutting property of high-strength hot-dip galvanized steel sheet can be improved.
Steel sheet thickness [0022] The thickness of the high-strength hot-dip galvanized steel sheet of the present invention is 0.6 to 5.0 mm. When the sheet thickness is less than 0.6 mm, it is difficult to maintain the shape of the flat steel sheet, which is not suitable. Therefore, the thickness of the plate is preferably 0.6 mm or more. In addition, when it is larger than 5.0 mm, the tendon that accompanies the fold does not occur and fine dispersion of bainite is difficult, making it difficult to generate a predetermined sheet steel structure. Therefore, the thickness of the steel sheet is preferably 5.00 mm or less.
Structure of the steel plate [0023] In the structure of the high-strength hot-dip galvanized steel plate of the present invention, in a range of 1/8 of the thickness to 3/8 of the thickness with 1/4 of the thickness of the plate being the center from the surface of the steel plate, the steel plate structure contains at least 40 to 90% of ferrite phase and 3% or more of austenite phase retained in fraction of volume. In addition, in the retained austenite phase, the amount of carbon in the solid solution in the
15/112 is 0.70 to 1.00%, the average grain diameter is 2.0 pm or less, and the average distance between grains is 0.1 to 5.0 pm.
Retained austenite phase [0024] The retained austenite phase is a structure that increases hardening capacity at work and improves strength and ductility and, in the present invention, the volume fraction of the retained austenite phase is 3% or more. In addition, to also increase ductility, the volume fraction of the retained austenite phase is preferably 5% or more, more preferably 7% or more. On the other hand, to obtain the retained austenite phase exceeding 30%, it is necessary to add a large amount of austenite stabilizing elements such as C and Mn, which considerably deteriorate the welding capacity. Therefore, in the present invention, the volume fraction of the retained austenite phase is preferably 30% or less. In addition, in view of the weldability, the volume fraction of the retained austenite phase is preferably 25% or less, more preferably 20% or less.
[0025] Note that in relation to the volume fraction of the retained austenite, the x-ray analysis is performed on an observation surface that is a surface parallel to the surface of the steel plate sheet and 1/4 of the thickness of the steel plate from the surface of the steel plate, and the area fraction is calculated, which can then be considered as the volume fraction of austenite retained in the range of 1/8 of the thickness to 3/8 of the thickness. Note that since in parallel with the surface of the steel sheet, the observation surface of the steel sheet can be adjusted to any position in the range of 1/8 of thickness to 3/8 of thickness with 1/4 of thickness of the steel plate being the center from the surface of the plate thickness.
[0026] To suppress the deterioration of the mechanical cutting property by the retained austenite phase, the steel sheet which is easily colored
16/112 by mechanical cutting can be done by removing the resistance of the martensite after being transformed by processing, limiting the amount of carbon in the solid solution of the retained austenite phase to make it easily transformable by light processing, and by suppressing the diameter average grain of the austenite phase retained to increase density.
[0027] In addition, the amount of elements to be dissolved solids in the retained austenite phase determines the stability of the retained austenite phase, and changes the amount of tension required for the retained austenite phase to become hard martensite. Thus, it is possible to control the hardening behavior at work by controlling the amount of element in the solid solution of the retained austenite phase, thus greatly improving the ability to fix the shape, ductility and tensile strength.
[0028] The amount of carbon in the solid solution in the retained austenite phase is 1.00% or less. When the amount of carbon in the solid solution in the retained austenite phase exceeds 1.00%, the retained austenite phase becomes excessively stable. When such a steel sheet is cut, the ductility of the surrounding ferrite structure deteriorates considerably and then becomes martensite, and the interface between ferrite and martensite separates easily, which is not preferable. In addition, when the retained austenite phase is efficiently transformed into martensite, the amount of carbon in the solid solution in the retained austenite phase is preferably 0.96% or less. On the other hand, when the amount of carbon in the solid solution in the retained austenite phase is less than 0.70%, the transformation of martensite begins in the cooling process to room temperature after the annealing step and the volume fraction of the austenite phase cannot be guaranteed, so the amount of carbon in the solid solution is 0.70% or more. In addition, to obtain a sufficient amount of phase
17/112 austenite retained, the amount of carbon in the solid solution is preferably 0.75% or more, more preferably 0.80% or more.
[0029] Note that the amount of carbon in the solid solution (Cy) in the retained austenite phase can be obtained by performing an x-ray diffraction test under the same conditions as the measurement of the area fraction of the retained austenite phase in order to obtain a number of lattice forms of the retained austenite phase, and using equation (1) below. Equation (1) is described in the document Scripta Metallurgica et Materialia, vol. 24, 1990, pgs. 509-514.
Equation 1 (a-0.3556) 12.01
G, = --------------------- - · · (ί>
^/ 0.00095 55.84 [0030] In addition, the method for measuring the amount of carbon in the solid solution is not limited to the method above. For example, a direct observation using an EMA method, a three-dimensional atom probe (3D-AP), or similar can be performed in order to measure the concentration of the respective types of elements.
[0031] In the retained austenite phase contained in the structure of the high-strength hot-dip galvanized steel sheet of the present invention, the amount of carbon in the solid solution in the phase is 0.70 to 1.00%, the average grain diameter is 2.0 pm or less, and the average distance between grains is 0.1 to 5.0 μιτι.
[0032] When the diameter of the crystal grains of the retained austenite phase is gross, the fracture that begins in the austenite occurs. Thus, in the present invention, the average diameter of the crystal grains of the retained austenite phase is defined to be 2.0 pm or less. In addition, the average grain diameter of the retained austenite phase is preferably 1.5 pm or less, more preferably 1.2 pm or less. Note that although the lower limit of the average grain diameter of the retained austenite phase is not particularly limited, special equipment such as a
18/112 laminating machine or fast heating equipment for applying a high voltage becomes necessary and the costs increase greatly, so it is preferably 0.1 pm or more.
[0033] In addition, when the distance between the crystal grains of the retained austenite phase is excessively separated, a gross fracture occurs between the austenite grains and the cutting property deteriorates, and thus it is necessary to make the distance between grains of the austenite small to induce numerous microfractures to improve cutting properties. Thus, according to the present invention, the average distance between grains of the retained austenite phase is more preferably 3.5 pm or less, preferably 2.5 pm or less. On the other hand, when the distance between the crystal grains of the retained austenite phase is very narrow, a fracture that occurred by an austenite or martensite grain generated by the transformation of the austenite grain easily spreads to an adjacent austenite or martensite grain by transforming the austenite grain, and thus several austenite grains come together and work effectively as an austenite grain. To separate austenite to act separately, it is necessary to have the average distance between grains of the austenite phase retained being 0.1 pm or more. In addition, the average distance between grains of the retained austenite phase is more preferably 0.3 pm or more, even more preferably 0.5 pm or more.
[0034] It is noted that the crystal grains of the retained austenite phase can be evaluated by the execution, in a cross section parallel to the direction of lamination and perpendicular to the surface of the plate, in the range of 1/8 of the thickness to 3/8 of the thickness with 1/4 of the plate thickness being the center from the steel plate surface, an analysis of the high resolution crystal orientation by an EBSD method (electron Back-Scatterinq Diffraction) using a microscope of
19/112 electronic field emission scanning (FE-SEM). For example, with a measurement step being set to 0.1 pm, the area where 10 or more points indicating an FCC iron diffraction pattern come together and the disorientation of the crystal in one or the other is less than 10 ° is considered like austenite crystal grain. Then, the average distance between grains can be measured in a range of 10000 pm ² or more by setting {average distance L between grains = ([observation areas] / [number of crystal grains]) ¹⁷² } or measured in a strip containing 150 or more retained austenite crystal grains. In addition, the average diameter of the crystal grain can be measured by obtaining the area of each crystal grain between 30 to 300 grains of retained austenite crystal chosen at random, and obtaining the grain diameter as an equivalent circle diameter.
Microstructure [0035] The structure of the high-strength hot-dip galvanized steel sheet of the present invention preferably has, in addition to the retained austenite phase described above, in fraction of volume, ferrite phase: 40 to 90%, bainitic ferrite phase and / or bainite phase: 50% or less, new martensite phase: 15% or less. The high-strength hot-dip galvanized steel sheet of the present invention becomes a steel sheet having a more excellent forming capacity because it has such a steel sheet structure.
(Ferrite Phase) [0036] The ferrite phase is an effective structure for improving ductility, and is preferably contained in 40 to 90% by volume fraction in the steel sheet structure. When the volume fraction of the ferrite phase in the steel plate structure is less than 40%, it is possible that sufficient ductility will not be obtained. In addition, in relation to the volume fraction of the ferrite phase contained in the steel plate structure, it is more preferably contained in 45% or more, more preferred
20/112 by 50% or more in view of ductility. On the other hand, since the ferrite phase is a soft structure, when its volume fraction exceeds 90%, it is possible that sufficient strength cannot be achieved. In addition, to sufficiently increase the tensile strength of the steel sheet, the volume fraction of the ferrite phase contained in the steel sheet structure is more preferably 85% or less, more preferably 75% or less.
(Bainitic ferrite phase and / or bainite phase) [0037] The bainitic ferrite phase and / or bainite phase is an excellent structure in balance between strength and ductility, and is preferably contained in 10 to 50% and volume fraction in the plate structure of steel. In addition, the bainitic ferrite phase and / or bainite phase has a microstructure that has a resistance that is in the middle between the soft ferrite phase and the hard martensite phase, tempered martensite phase and retained austenite phase, and they are more preferably contained in 15 % or more, more preferably 20% or more in view of the forming capacity of the flange in the drawing. On the other hand, when the volume fraction of the bainitic ferrite phase and / or bainite phase exceeds 50%, the yield strength increases excessively and the fixation capacity of the shape deteriorates, which then is not preferable.
(Tempered martensite phase) [0038] The tempered martensite phase is a structure that greatly improves the tensile strength, and can be contained by 50% or less in volume fraction in the steel plate structure. In view of the tensile strength, the volume fraction of the tempered martensite is preferably 10% or more. On the other hand, when the volume fraction of tempered martensite contained in the steel sheet structure exceeds 50%, the elasticity limit increases excessively and there is a concern of deterioration of the shape's fixing capacity, which is not preferable.
21/112 (New martensite phase) [0039] The new martensite phase has the effect of greatly improving the tensile strength, but on the other hand it becomes a starting point of destruction and greatly deteriorates the flanging capacity in stretching. Consequently, it is preferably limited to 15% or less in volume fraction in the steel sheet structure. To increase the flanging capacity in elongation, the volume fraction of the new martensite phase in the steel sheet structure is more preferably 10% or less, even more preferably 5% or less.
(Other microstructures) [0040] The structure of the high-strength hot-dip galvanized steel sheet of the present invention may also contain a structure such as a pearlite phase and / or a crude cementite phase in addition to the structures described above. However, when there is a large amount of pearlite phase and / or crude cementite phase the structure of the high strength steel plate, the problem arises that the ductility deteriorates. Thus, the volume fraction of the pearlite phase and / or of the crude cementite phase contained in the steel sheet structure is preferably 10% or less, more preferably 5% or less in total.
Steel plate structure measurement method [0041] The volume fraction of the respective structures contained in the high strength steel plate structure of the present invention can be measured, for example, by the method described below.
[0042] When measuring the volume fractions of the ferrite phase, the bainitic ferrite phase, the bainite phase, the tempered martensite phase and the new martensite phase contained in the structure of the hot-dip galvanized steel sheet of high resistance to the present invention , initially a sample is collected from an observation surface which is the cross section parallel to the rolling direction and perpendicular
22/112 to the surface of the steel sheet. Then, this sample observation surface is polished and etched with nital, and the range of 1/8 of the thickness to 3/8 of the thickness with ¹ Λ of the thickness of the plate being the center from the surface of the steel plate is observed with a scanning electron microscope with field emission and the area fractions are measured, which can be considered as the volume fractions of the respective structures.
Composition of the chemical components [0043] The following describes the chemical components (composition) of the high-strength hot-dip galvanized steel sheet of the present invention. Note that [%] in the description below represents [% by mass] unless specifically specified.
C: 0.075 to 0.400% [0044] C is contained to increase the strength of the high strength steel sheet. However, when the C content exceeds 0.400%, the welding capacity becomes insufficient, and so it is preferably 0.400% or less. In addition, in view of the weldability, the C content is preferably 0.250% or less, more preferably 0.220% or less. On the other hand, when the C content is less than 0.075%, the strength decreases and it becomes difficult to guarantee the maximum tensile strength of 900 MPa or more. From that point of view, to also increase the strength of the steel sheet, the C content is more preferably 0.085% or more, even more preferably 0.100% or more.
Si: 0.01 to 2.00% [0045] Si is an element that suppresses the generation of iron-based carbide in the steel plate, and increases strength and forming capacity. However, when the Si content exceeds 2.00%, the steel sheet becomes brittle and the ductility deteriorates, making it difficult
23/112 the lamination. In view of ductility, the Si content is preferably 1.80% or less, more preferably 1.50% or less. On the other hand, when the Si content is less than 0.01%, it becomes difficult to sufficiently disperse the oxides in the decarburized layer. In view of this, the lower limit value of Si is more preferably 0.20% or more, even more preferably 0.50% or more.
Mn: 0.80 to 3.50% [0046] Mn is added to increase the strength of the steel plate. However, when the Mn content exceeds 3.50%, a portion of concentrated crude Mn occurs in a central portion of the steel sheet, embrittlement occurs easily, and a problem such as breaking of a cast plate occurs easily. In addition, when the Mn content exceeds 3.50%, the welding capacity also deteriorates. Therefore, the Mn content needs to be 3.50% or less. Furthermore, in view of the weldability, the Mn content is more preferably 3.0-% or less, even more preferably 2.70% or less. On the other hand, when the Mn content is less than 0.80%, a large amount of soft structures is formed during cooling after annealing, and thus it is difficult to guarantee the maximum tensile strength of 900 MPa the most. Thus, the Mn content must be 0.80% or more. In addition, to also increase the strength, the Mn content is more preferably 1.00% or more, even more preferably 1.30% or more.
P: 0.0001 to 0.100% [0047] P tends to segregate in the central portion of the steel plate thickness, and weakens the welding zone. When the P content exceeds 0.100%, the welding zone becomes very fragile, and thus the upper limit of the P content is 0.100%. In order to avoid weakening the welding zone, the upper limit of the P content is more preferably 0.030% or less. On the other hand, adjust the P content to less than
24/112
0.0001% brings a big increase in production costs, and so
0.0001% is set as the lower limit value. In addition, the
P in order to also reduce production costs is preferably
0.0010% or more.
S: 0.0001 to 0.0100% [0048] S adversely affects the welding capacity and the production capacity during casting and hot rolling, and so the upper limit value of the S content is 0.0100% or any less. In addition, S binds to Mn to form crude MnS and decreases ductility and flanging capacity in the stretch, and thus its content is more preferably 0.0050% or less, more preferably 0.0030% or less. On the other hand, adjusting the S content to less than 0.0001% brings about a large increase in production costs, and so 0.0001% is adjusted as the lower limit value. In addition, the S content, in order to reduce production costs, is more preferably 0.0005% or more, yet honeys preferably 0.0010% or more.
Al: 0.001% to 2.00% [0049] Al suppresses the generation of iron-based carbides to increase the strength and forming capacity of the steel plate. However, when the Al content exceeds 2.00%, the welding capacity worsens, and thus the upper limit of the Al content is 200%. Furthermore, from that point of view, the Al content is more preferably 1.20% or less. Although the effects of the present invention are exhibited without particularly adjusting the lower limit of the Al content, Al is an inevitable impurity that exists in a small amount in a raw material, and adjusting its content to less than 0.001% brings a large increase production costs. Thus, the Al content is 0.001%. Al is also an effective element as a deoxidizing element, and the Al content is more preferably 0.010% or more to obtain the deoxidation effect more sufficiently.
25/112
Ν: 0.0001 to 0.0100% [0050] Ο Ν forms a crude nitride and deteriorates ductility and flanging capacity in the stretch, so its added quantity must be suppressed. When the N content exceeds 0.0100%, this trend becomes significant, and thus the upper limit of the N content is 0.0100%. Furthermore, from that point of view, the N content is more preferably 0.0070% or less, even more preferably 0.0050% or less. N also causes the generation of bubbles during welding, so the lower the content, the better. Although the effects of the present invention are presented without particularly adjusting the lower limit of the N content, adjusting the N content to less than 0.0001% brings about a large increase in production costs, and thus its content is 0.0001% or more. In addition, the N content in view of reducing production costs is more preferably 0.0005% or more, even more preferably 0.0010% or more.
O: 0.0001 to 0.0100% [0051] O forms an oxide and deteriorates the ductility and flanging capacity in the stretch, so its content needs to be suppressed. When the O content exceeds 0.0100%, the deterioration of the stretching flanging capacity becomes significant, and thus the upper limit of the O content is 0.0100%. In addition, the O content is more preferably 0.0070% or less, even more preferably 0.0050% or less. Furthermore, although the effects of the present invention are presented without particularly adjusting the lower limit of the O content, adjusting the O content to less than 0.0001% brings about a large increase in production costs, and thus 0.0001% is adjusted as p its lower limit. In addition, the O content in order to also reduce production costs is more preferably 0.0003% or more, even more preferably 0.0005% or more.
[0052] High-temperature hot-dip galvanized steel sheet
The strength of the present invention may also employ a structure including the following elements, if necessary.
Cr: 0.01 to 2.00% [0053] Cr is an element that suppresses the phase transformation at a high temperature and is effective in increasing resistance, and can be added instead of part of C and / or Mn. When the Cr content exceeds 2.00%, the working capacity during hot work is impaired and productivity decreases, and therefore the Cr content is preferably 2.00% or less. It is noted that although the effects of the present invention are presented without particularly adjusting the lower limit of the Cr content, the content is preferably 0.01% or more to sufficiently obtain the effect of increasing the resistance by Cr.
Ni: 0.01 to 2.00% [0054] Ni is an element that suppresses the phase transformation at a high temperature and is effective in increasing resistance, and can be added instead of part of C and / or Mn. When the Ni content exceeds 2.00%, the welding capacity is impaired, and thus the Ni content is preferably 2.00% or less. It is noted that although the effects of the present invention are presented without particularly adjusting the lower limit of the Ni content, the content is preferably 0.01% or more to sufficiently obtain the effect of increasing the resistance by Ni.
Cu: 0.01 to 2.00% [0055] Cu is an element that increases the resistance due to the existence of fine grains in steel, and can be added instead of part of C and / or Mn. When the Cu content exceeds 2.00%, the welding capacity is impaired, so the content is preferably 2.00% or less. It is noted that although the effects of the present invention are presented without particularly adjusting the lower limit of the Cu content, the content is preferably 0.01% or more to sufficiently obtain the e27 / 112 made of increased resistance by Cu.
Ti: 0.001 to 0.150% [0056] Ti and an element that contributes to increase the strength of the steel sheet by reinforcing precipitation, reinforcing the fine grain by suppressing the growth of ferrite crystal grains, and reinforcing the displacement through suppression of recrystallization. However, when the Ti content exceeds 0.150%, the precipitation of the carbonitrides increases and the forming capacity deteriorates, and thus the Ti content is preferably 0.150% or less. In addition, in view of the forming capacity, the Ti content is more preferably 0.100% or less, even more preferably 0.070% or less. It is noted that although the effects of the present invention are presented without particularly adjusting the lower limit of Ti, the Ti content is preferably 0.001% or more, more preferably 0.005% or more to sufficiently obtain the effect of increasing the resistance by Ti. In addition, to increase the strength of the steel sheet, the Ti content is more preferably 0.010% or more, still more preferably 0.015% or more.
Nb: 0.001 to 0.100% [0057] Nb is an element that contributes to reinforce the resistance of the steel sheet by reinforcing the precipitate, reinforcing the fine grain by suppressing the growth of ferrite crystal grains, and reinforcing the displacement through suppression recrystallization. However, when the Nb content exceeds 0.150, the precipitation of the carbonitrides increases and the forming capacity deteriorates, and thus the Nb content is preferably 0.150% or less. Furthermore, in view of the conformability, the Nb content is more preferably 0.100% or less, even more preferably 0.060% or less. It is noted that although the effects of the present invention are presented without particularly adjusting the lower limit of the Nb content, the Nb content is
28/112 preferably 0.001% or more, even more preferably 0.005% or more to sufficiently obtain the effect of increasing the resistance by Nb. In addition, to increase the strength of the steel sheet, the Nb content is more preferably 0.010% or more, even more preferably 0.015% or more.
V: 0.001 to 0.300% [0058] V is an element that contributes to increase the strength of the steel sheet by reinforcing precipitation, reinforcing fine grain by suppressing the growth of ferrite crystal grains, and reinforcing displacement through suppression of recrystallization. However, when the V content exceeds 0.300%, the precipitation of the carbonitride increases and the forming capacity deteriorates, and thus the content is preferably 0.300% or less. It is noted that although the feats of the present invention are presented without particularly adjusting the lower limit of the V content, the content is preferably 0.001% or more to obtain sufficiently the increase in resistance or the effect of increasing resistance by V.
Mo: 0.01 to 2.00% [0059] Mo is an element that suppresses the phase transformation at high temperature and is effective in increasing resistance, and can be added instead of part of C and / or Mn. When the Mo content exceeds 2.00%, the working capacity during hot work is impaired and productivity decreases, and thus the Mo content is preferably 2.00% or less. More preferably 1.00% or less. It is noted that although the effects of the present invention are presented without particularly adjusting the lower limit of the o content, the content is preferably 0.01% or more to sufficiently obtain the effect of increasing the resistance by Mo.
W: 0.01 to 2.00% [0060] W is an element that suppresses the phase-to-transformation
29/112 high temperature and is effective for increasing strength, and can be added in place of C and / or Mn. When the W content exceeds 2.00%, the working capacity during hot work is impaired and productivity decreases, and thus the W content is preferably 2.00% or less, even more preferably 1.00% or any less. It is noted that although the effects of the present invention are presented without particularly adjusting the lower limit of W, the content is preferably 0.01% or more to sufficiently obtain the effect of increasing the resistance by W.
B: 0.0001 to 0.0100% [0061] B is an element that suppresses the phase transformation at high temperature and is effective for increasing resistance, and can be added in the moonlight of part of C and / or Mn. When the B content exceeds 0.0100%, the workability during hot work is impaired and productivity decreases, and thus the B content is preferably 0.0100% or less. Furthermore, in view of productivity, the B content is more preferably 0.0050% or less, even more preferably 0.0030% or less. It is noted that although the effects of the present invention are presented without particularly adjusting the lower limit of the B content, the B content is preferably 0.0001% or more to sufficiently obtain the effect of increasing the resistance by B. Furthermore , to also increase the strength of the steel sheet, the B content is more preferably 0.0003% or more, more preferably 0.0005% or more.
0.0001 to 0.0100% in total of one or more elements between Ca, Ce, Mg, Zr, La, and REM [0062] In the high-strength hot-dip galvanized steel sheet of the present invention, like other elements , 0.001 to 0.5000%, more preferably 0.0001 to 0.0100% in total of one or more elements between Ca, Ce, Mg, Zr, La, and REM can be added
30/112 of. The reasons for adding these elements are as follows. [0063] Ca, Ce, Mg, Zr, La, and REM are effective elements to improve the conformability, and one or more of them can be added. However, when the total content of one or more between Ca, Ce, Mg, Zr, La, and REM exceeds 0.5000%, it is possible that ductility is impaired, and thus the total content of the elements is preferably 0.5000% or less, more preferably 0.0100% or less. The effects of the present invention are presented without particularly adjusting the lower limit of the content of one or more elements between Ca, Ce, Mg, Zr, La, and REM, the total content of these elements is preferably 0.0001% or more to obtain sufficiently the effect of improving the forming capacity of the steel sheet. In view of the confirmatory capacity, the total content of one or more elements between Ca, Ce, Mg, Zr, La, and REM is more preferably 0.0005% or more, more preferably 0.0010% or more. Note that REM means Metal Terra Rara, and refers to an element that belongs to the series of lantanoids. In the present invention, REM or Ce is often added in metal misch, and may contain elements from the series of lantanoids other than La and Ce in a complex form. The effects of the present invention are presented even when elements of the series of lantanoids other than La and Ce are contained as unavoidable impurities. In addition, the effects of the present invention are shown even when the metals La and CE are added.
[0064] The balance of the above elements may consist of Fe and the inevitable impurities. Note that in relation to any element between Cr, Ni, Cu, Ti, Nb, V, Mo, W, B described above, it contains a very small amount less than the lower limit values as impurities is tolerated. In addition, in relation to Ca, Ce, Mg, Zr, La, and REM, contain an ultra-micro-less amount than the lower limit values of their total amounts as impurities is tolerated.
1/31
Portion of the surface layer of the steel sheet [0065] In the high-strength hot-dip galvanized steel sheet of the present invention, the thickness of the decarburized layer in the portion of the surface layer of the steel sheet is 0.01 to 10, 0 pm, and the average grain diameter of the oxides contained in the surface layer portion of the steel sheet is 30 to 120 nm and the average density is 1.0 χ 10 ¹² oxides / m ² or more.
Decarburized layer [0066] In the present invention, to increase the adherence capacity of a coating layer to be supplied on the surface of the steel sheet, the surface layer portion of the steel sheet is an unburdened layer in which a hard structure is small. When the thickness of this decarburized layer is less than 0.01 pm, the adhesion capacity of the coating layer cannot be obtained sufficiently, and thus the thickness of the decarburized layer is 0.01 pm or more. To also improve the tackiness of the coating layer, the thickness of the decarburized layer is more preferably 0.08 pm or more, even more preferably 0.15 pm or more. On the other hand, the decarburized layer that is excessively thick decreases the tensile strength and the fatigue resistance of the steel sheet. From this point of view, the thickness of the decarburized layer on the surface portion of the steel plate is 10.0 pm or less. In addition, in view of the fatigue strength, the thickness of the decarburized layer is more preferably 9.0 pm or less, even more preferably 8.0 pm or less.
[0067] Note that the decarburized layer described in the present invention refers to an area that is continuous from the uppermost surface of the base iron surface, and in that area the fraction of a hard structure is half or less than the fraction of a structure lasts 1/4 of the thickness. Furthermore, in relation to the thickness of the layer
32/112 carburized, the cross section parallel to the rolling direction of the steel sheet and perpendicular to the surface of the sheet is polished mirrored and observed using FE-SEM, the thickness of the decarburized layers of three or more positions are measured in one steel plate, and its average value is taken as the thickness of the decarburized layer. Note that the hard structure described in the present invention refers to a structure consisting of a phase, but harder than ferrite, that is, a structure consisting mainly of a phase of bainite, bainitic ferrite, martensite and tempered martensite, retained austenite and / or similar. In addition, its fraction is using the volume fraction.
Oxides [0068] In the decarburized layer, oxides containing Si and / or Mn are dispersed in crystal grains and / or edges of crystal grains to increase the cutting property so that mechanical cutting can be easily performed. The higher the density of the oxides, the more the cutting property is improved, and thus, in the present invention, the density of oxides is 1.0 χ 10 ¹² oxides / m ² or more. In addition, from the above point of view, the oxide density is more preferably 3.0 χ 10 ¹² oxides / m ² or more, even more preferably 5.0 χ 10 ¹² oxides / m ² or more. On the other hand, when the oxide density exceeds 1.0 χ 10 ¹⁶ oxides / m ² , the distance between oxides becomes excessively close, the surface layer portion of the steel plate breaks by light processing and, in addition, the coating layer is damaged. Thus, the oxide density is preferably limited to 1.0 χ 10 ¹⁶ oxides / m ² or less. In addition, to ensure sufficient forming capacity in the surface layer portion of the steel plate, the density of the oxides is more preferably 5.0 χ 10 ¹⁵ oxides / m ² or less, even more preferably 1.0 χ 10 ¹⁵ oxides / m ² or less.
33/112 [0069] In addition, the oxides dispersed in the surface layer portion of the steel sheet do not contribute to improving the cutting property when they are excessively small, and thus the average diameter of the oxide grains is defined as being 30 nm or more in the present invention. On the other hand, when the oxides are excessively crude, fracture characteristics, such as ductility, are impaired, and thus the average diameter and grain of the oxides is 500 nm or less. Furthermore, from that point of view, the average grain diameter of the oxides is more preferably 300 nm or less, even more preferably 120 nm or less, and even more preferably 100 nm or less. In addition, in order to make the average grain diameter of the oxides less than 30 nm, the atmosphere and temperature of the treatment need to be strictly controlled making this practically difficult, and so it is preferably 30 nm or more.
[0070] Regarding the oxides in the surface layer portion of the steel plate as described above, the cross section parallel to the rolling direction of the steel plate and perpendicular to the surface of the steel plate is polished mirrored and observed using a FESEM. The density of the oxides is obtained by observing the decarburized layer for an amount of 7 pm ² and counting the number of oxides, or obtained using an observation area that is necessary until 1000 oxides are counted. In addition, regarding the size of the oxides, 100 to 1000 diameters of random equivalent circles are measured, and their average diameter is taken.
Coating layer [0071] In the present invention, on the surface of a steel sheet having the above structure, a hot dip galvanized layer or an attached hot dip galvanized layer is formed to form a galvanized steel sheet high-resistance hot-dip or a galvanized steel sheet
34/112 hot-dip bonded high strength. Thus forming the hot-dip galvanized layer on the surface of the steel sheet, a high-strength hot-dip galvanized steel sheet can be obtained having excellent corrosion resistance. In addition, by forming the hot-dip galvanized layer bonded to the surface of the steel sheet, a high-strength hot-dip galvanized steel sheet can be obtained that has excellent corrosion resistance and is excellent in adhesion capacity of ink.
Mechanical cutting property [0072] The mechanical cutting property in the present invention can be measured and evaluated, for example, by the method described below.
[0073] Generally, when a cut or a punch with a punch is performed several times on the high-strength steel plate, the cutting blade or the punch tip wears out and the clearance increases. Thus, when the number of times the punch of a steel plate increases, the burrs on the cut surface and on the punctured surface become large. Consequently, as a method for assessing the mechanical cutting property of high-strength hot-dip galvanized steel sheet in accordance with the present invention, a method that continuously punctures and measures burr heights every 50 times under the conditions of the steel sheet is 1.2 mm thick, a mold having a bore diameter of 10.3 mmcp, an SKD11 punch material, a puncture diameter of 10 mmcp (clearance 12.5%).
[0074] In the evaluation by the method above, it was found that when the number of times the punching of the steel plate increases, the tip of the punch wears out and the clearance increases, and thus the height of the burr increases. However, as a result of repeated measurement,
35/112 depending on the case, cases were seen in which the height of the burr varied significantly on a specific face of a steel plate. Consequently, the anointing holes are divided into four at the 0 °, 90 °, 180 °, 270 ° positions, and at a point where the burr height in the direction of one of them exceeds 3.0 times the initial value, the The test is ended and the number of times the punch is defined as the limit number of times the punch. Describing more specifically, when measuring the burr height of a punctured hole, the maximum burr height in the range of 0 ^o to 90 ° is h1, the maximum burr height in the range of 90 ° to 180 ° is h2, the maximum height of the burr in the range of 180 ° to 270 ° is h3, the maximum height of the burr in the range of 270 ° to 360 ° is h4. Considering that the height of the burr when first punctured is h1 *, h2 *, h3 *, h4 *, the number of times the puncture at a point where one or more between h1 / h1 *, h2 / h2 *, h3 / 3h *, h4 / h4 * exceeds 3.0 is the limit number of times for punching. Note that, in the punching test, the test is performed so that the relative directions in the direction of the cold rolling of a puncher, a mold, and a non-modem steel plate, and the direction of travel of the cold rolling between the rolling directions of the steel sheet is 0 ^o . In the present invention, a sheet in which the number of times the punching exceeds 600 times can be defined as a high-strength hot-dip galvanized steel sheet with excellent mechanical cutting properties. More preferably the limit number of times of the punch is 800 times, even more preferably 1000 times. Hardening coefficient at work (n value) [0075] In the high resistance hot-dip galvanized steel sheet defined in this configuration, the work hardening coefficient (n value) at the time of plastic deformation of 3 to 7% is 0.080 or more on average.
36/112 [0076] As described above, the hardening coefficient at work (value n) defined in the present invention is a characteristic value to be the reference of the stamping property (ductility), and the higher the value n, the greater the extension to the place where the contraction occurs, thus improving ductility. However, on the other hand, there is the contradictory characteristic that the lower the n value, the more the mechanical cutting property improves.
[0077] In the present invention, the value n with which ductility is improved is defined to be 0.080 or more. On the other hand, although the upper limit of the value n is not particularly defined, to make the value n at the time of a plastic deformation of 3 to 7% be greater than 0.250 on average. It is necessary to make the maximum tensile strength less than 900 MPa or to add a 0.40% C amount, which is not preferable. In that view, the value n is preferably 0.200 or less, more preferably 0.18 or less in view of the particular tensile strength. It is noted that the plastic deformation of 3 to 7% is in the plastic working range of a steel plate that is often used normally.
[0078] In the present invention, as described above, the hardening capacity at work is increased by containing the austenite phase retained in the steel plate structure by 3% or more, and has high ductility with the value n being 0.080 or more in average. On the other hand, in the present invention, the amount of carbon in the solid solution in the retained austenite phase is limited to 0.70 to 1.00%, and the average grain diameter is suppressed to 2.0 pm or less, and the distance mean between grains is suppressed to 5.0 pm, in order to increase the density and, therefore, improve the mechanical cutting property. Thus, it is possible to obtain both excellent ductility and mechanical cutting property while ensuring high tensile strength.
37/112
Maximum tensile strength [0079] In the present invention, it is preferable that the maximum tensile strength is 900 MPa or more as steel plate strength. This is because it is the resistance that makes tool deterioration significant when shearing or punching is performed on a high-strength steel plate of 900 MPa or more. In addition, even on a steel sheet of less than 900 MPa, the effect of improving the mechanical cutting property that is an effect of the present invention can be used, but the effect is small on a steel sheet with low tensile strength . Consequently, in the present invention, together with the above effect, also in order to guarantee the strength of the base material, it is preferable to apply a high-strength hot-dip galvanized steel sheet of 900 MPa or more.
Production method of the high-strength hot-dip galvanized steel sheet [0080] The production method of the high-strength hot-dip galvanized steel sheet excellent in forming capacity of the present invention will be described below.
[0081] The production method of the high strength hot dip galvanized steel sheet of this configuration initially includes a hot rolling step of heating to 1180C or more a plate having the chemical components described above directly or after cooling once and perform hot rolling where the rolling finish temperature is 850 to 950Ό, then cool quickly to 500 to 650Ό at an average cooling rate of 10 lbs / s or more, and then wind in a coil and cool slowly up to 400Ό taking an hour or more, and a cold rolling step to perform cold rolling so that the total reduction ratio is 30 to 75% after sub blasting
38/112 following the hot rolling step. In addition, in this configuration, an annealing step of heating the steel sheet after the cold rolling step to 750Ό or more is also included with the average heating rate between 600 and 750Ό being 20O / s or less, and then cooling with the average cooling rate between 750 and 650Ό being 1.0 to Ιδ, Ο'Ό / ε and cooling with an average cooling rate from 650Ό being 3.0Ό // 8 or more, and run, while retains for 20 to 1000 seconds in the temperature range of 300 to 470Ό and while a tension of 5 to 100 MPa is applied in that temperature range, one or more folding times with a folding radius of 800 mm or less. In addition, in this configuration, a coating step of carrying out hot dip galvanization on the steel sheet surfaces is also included to form a coating layer by immersing the steel sheet, after the annealing step, in a bath of galvanizing under the conditions of the coating bath: 450 to 470Ό, temperature of the steel plate at the time of entering the coating bath: 430 to 490Ό, and effective amount of Al in the coating bath: 0.01 to 0.18 % in large scale. In addition, in this configuration, a cooling step is also included at an average cooling rate of Ο, δ'Όιε or more at 150O / S or less after the coating step. So, in this configuration, as the annealing step, a method is used such that, in a preheating zone under the condition of an air ratio: 0.7 to 1.2 in a mixed air and combustible gas used in a preheat burner, the air ratio being the ratio of the volume of air contained in the mixed gas in one volume unit and the volume of air logically necessary for the complete combustion of the fuel gas contained in the mixed gas in the volume unit, are generated oxides in a portion of the steel sheet's surface layer through the passage while heating to
39/112 a steel plate temperature of 400 to 800Ό, so the oxides generated in the preheating zone are reduced by heating up to 750Ό or more in a reduction zone with the partial pressure ratio P (H ₂ O) / P (H ₂ ) between water vapor (H ₂ O) and hydrogen (H ₂ ):
0.0001 to 2.0, and then cooling is performed.
[0082] To produce the high-strength steel plate of the present invention described above, initially a plate having the chemical components (composition) described above is cast.
[0083] As the slab to be subjected to hot rolling, a slab can be used continuously or a slab produced by a thin slab caster, or similar. The production method of the high-strength galvanized steel sheet of the present invention is compatible with a process such as direct continuous rolling casting (CC-DR) in which hot rolling is performed immediately after casting.
[0084] In the hot lamination step of this configuration, to smooth the anisotropy of a crystal orientation due to casting, the heating temperature of the plate is 1180Ό or more. In addition, the heating temperature of the plate is more preferably 1200Ό or more. The upper limit of this plate heating temperature is not particularly adjusted, but the heating temperature is preferably 1300Ό or less because a large amount of energy must be used to heat above 1300Ό.
[0085] After the plate is heated to the above temperature, hot lamination is performed. In the present invention, the hot rolling finish temperature is 850 to 950Ό. When this lamination termination temperature is less than 850Ό, the lamination reaction is greatly increased to increase the loading step, and so in the present invention this temperature is 850Ό or more, more preferred
40/112 870Ό or more. On the other hand, when the finishing temperature of the rolling mill exceeds 950Ό, the microstructure in hot rolled steel becomes rough, and the microstructure in cold rolling and in the subsequent annealing steps also becomes rough. Thus, in the present invention, the termination temperature of the lamination is 950Ό or less, more preferably 930Ό or less.
[0086] After hot lamination, it is quickly cooled (rapid cooling). In the present invention, the average rate of cooling when the rapid cooling is performed to 500 or 600Ό is preferably 10 pounds / s or more. This is to advance the transformation at lower temperatures to micronize the grain diameter of the hot-rolled steel sheet, and micronize the effective crystal grain diameter after cold rolling and annealing. On the other hand, the upper limit of the average cooling rate is not particularly adjusted, but when it exceeds 200O / S a special cooling medium is required which is not preferable in terms of costs. Thus, this limit is preferably 200O / S or less.
[0087] After the steel sheet is quickly cooled, it is wound as a hot-rolled coil. In this stage, perlite and / or crude cementite whose major axis exceeds 1 pm is / are generated in the steel sheet after hot rolling, to thereby randomize the textures and modes of various types of structures transformed in the stage of annealing after cold rolling, which will be described later. In order to generate crude perlite and / or cementite in this way, the stop temperature of the rapid cooling after hot rolling is 500Ό or more in the present invention. In addition, to decrease anisotropy, the cooling stop temperature is more preferably 530Ό or more, even more preferably 550Ό or more. On the other hand, when the cooling stop temperature is very high, the scale layer of the portion of the surface layer
41/112 of the steel sheet becomes excessively thick and the quality of the surface is impaired, so the cooling stop temperature must be 650Ό or less in the present invention. In addition, from the above point of view, the cooling stop temperature is preferably 630Ό or less. Then, in the present invention, the steel sheet for which the above cooling stop temperature is 500 to 650Ό is cooled as a hot rolled coil.
[0088] In addition, in order to sufficiently generate the crude perlite and / or cementite and reduce the anisotropy of the delayed fracture resistance, retention is necessary for a sufficient time in the temperature range in which the cementite is generated after rapid cooling. be terminated. Consequently, in the present invention, the time passed for slow cooling since stopping the cooling at 400 ° is 1.0 hour or more. In addition, that time is more preferably 2.0 hours or more, more preferably 3.0 hours or more. In addition, the upper limit of time spent is not particularly just, but a retention above 24.0 hours requires special equipment, which is not preferable in terms of costs. Thus, it is preferably 24.0 hours or less.
[0089] Then, in this configuration, the hot-rolled steel sheet produced under the above conditions is subjected to a pickling treatment. Pickling is capable of removing oxides from the surfaces of steel sheets, and so it is important from the point of view of improving the galvanizing properties of high-strength hot-dip galvanized steel sheet or hot-dip galvanized steel sheet bonded high strength as a final product. In addition, pickling can be just one treatment or can be carried out through several separate treatments.
[0090] Then the steel sheet after pickling is laminated so that the total reduction ratio becomes 30% or more and 75% or
42/112 less by cold rolling. At that time, lamination is preferably carried out through several paths, and the number of lamination paths and the distribution of the reduction ratio for the paths are not in question. When the ratio of reduction in cold rolling becomes less than 30%, sufficient stress is not accumulated on the steel sheet, and thus recrystallization does not happen sufficiently through a subsequent annealing step and a processed structure is left in the state, making the structure gross. Thus, the average distance between grains in the retained austenite phase becomes large and the cutting property deteriorates. In addition, in order to sufficiently build up the tension, the total reduction ratio is more preferably 33% or more, even more preferably 36% or more. On the other hand, when the total reduction ratio exceeds 75%, there are cases where the steel sheet breaks during rolling, and thus the total reduction ratio in cold rolling is 75% or less in the present invention. Furthermore, from the above point of view, the total reduction ratio is more preferably 70% or less, even more preferably 65% or less.
[0091] Next, in the present invention, for the steel sheet under the above conditions, the annealing treatment is performed in an annealing step under the following conditions, and then the hot dip galvanizing treatment is performed in a coating step. In the present invention, a continuous annealing and coating line having a preheating zone, a reduction zone and a coating zone is preferably used for the annealing step and the coating step. In addition, the atmosphere of the preheating zone can be any one between an oxidation atmosphere, a non-oxidation atmosphere, and a direct reduction atmosphere.
[0092] As described above, when the continuous annealing and coating line is used for the annealing step and the eta
43/112 pa of coating, like the annealing step under the conditions above, a method such that, in a preheating zone under the air ratio conditions: 0.7 to 1.2 in a mixed gas air and fuel gas used in a preheat burner, the air ratio being the ratio of the volume of air contained in the mixed gas in a volume unit and the volume of air logically necessary to complete the combustion of the combustible gas contained in the mixed gas in the volume unit, oxides are generated in the surface layer portion of the steel sheet through the passage while heating to the steel sheet temperature of 400 to 800Ό, then the oxides generated in the preheating zone are reduced by heating to 750Ό or more in a reduction zone with a partial pressure ratio P (H ₂ O) / P (H ₂ ) between H ₂ O and H ₂ : 0.0001 to 2.0, and then cooling is performed. Then, the coating step after the annealing step can be a method that performs hot dip galvanizing under the conditions that the steel sheet is immersed in a galvanizing bath under the temperature conditions of the coating bath: 450 at 470Ό, temperature of the steel plate at the time of entering the coating bath: 430 to 490Ό, and the effective amount of Al in the coating bath: 0.01 to 0.18% by weight.
[0093] The rate of heating in the annealing step affects the recrystallization behavior on the steel plate. In particular, the heating rate at 600 to 750Ό is important, and by adjusting the average heating rate to 20O / s or less, recrystallization takes place sufficiently to make the microstructure isotropic and thin. In addition, for recrystallization to also take place, the average heating rate is more preferably 15 O / s or less, even more preferably 12 O / S or less. It is noted that the lower limit of the average rate of heating is not particularly adjusted, but the
44/112 activity decreases significantly when the average heating rate is less than 0.5Ό / ε, and so it is preferably 0.5Ό / ε or more, [0094] In the preheat zone, an oxidation treatment is performed to form a Fe oxide coating film having a suitable thickness in the surface layer portion of the steel sheet. At that time, the temperature of the steel sheet when it passes in the preheating zone is adjusted to 400 to 800O, and preheating under the condition that the air ratio {[ratio, in a mixed air to combustible gas used in a preheat burner, the volume of air contained in the mixed gas at an age of volume and the volume of air logically necessary for the complete combustion of the combustible gas contained in the mixed gas in volume unit] = [volume of air contained in the mixed gas in volume unit (m ³ )] / [volume (m ³ ) of air logically necessary for the complete combustion of combustible gas contained in the mixed gas in the volume unit]} is 0.7 to 1.2, the film of Fe oxide coating from 0.01 to 20 pm is formed in a surface layer of the steel plate. When the air ratio is too large exceeding 1.2, a sufficient Fe oxide coating film is not generated in the surface layer portion of the steel sheet. In addition, since the oxide coating film works as a source of oxygen supply to generate oxides of Si and / or Mn in the reduction zone, when the air ratio is less than 0.7, which is very small, oxides predetermined values cannot be obtained. In addition, if the temperature of the steel sheet when it passes in the preheating zone is less than 400Ό, it is not possible to form a sufficient oxide coating film or, on the other hand, when it is a high temperature exceeding 800Ό, the coating film of oxide grows excessively, and thus it becomes difficult to make the thickness of the decarburized layer fall within a predetermined range.
45/112 [0095] In addition, when the maximum heating temperature in the annealing stage is low, the crude cementite melts and remains, which significantly deteriorates the ductility. In the present invention, to sufficiently dissolve cementite to ensure ductility, the maximum heating temperature is 750 é or more, more preferably 760Ό or more. Note that the upper limit of the heating temperature is not particularly limited, but heating above 1000Ό greatly impairs the surface quality and deteriorates the wetting of the coating, and thus the maximum heating temperature is preferably 1000Ό or less, more preferably 950Ό or less.
[0096] The maximum heating temperature (750Ό or more) in the annealing step is preferably reached in the reduction zone. In this reduction zone, the iron oxide coating film generated in the oxidation zone is reduced to form the decarburized layer, and oxides of Si and / or Mn are sparingly dispersed. Thus, in the atmosphere of the reduction zone, the ratio between the partial pressure of water vapor P (H ₂ O) and the partial pressure of hydrogen P (H ₂ ), P (H ₂ O) / P (H ₂ ) , is preferably 0.0001 to 2.00. When P (H ₂ O) / P (H ₂ ) is less than 0.0001, the oxides of Si and / or Mn are formed only in the uppermost surface layer, and it becomes difficult to disperse the oxides of Si and / or Mn moderately within the decarburized layer. On the other hand, when P (H ₂ O) / P (H ₂ ) exceeds 2.00, the decarburization happens excessively, and it is possible that the thickness of the decarburized layer cannot be controlled in a predetermined range. In addition, P (H ₂ O) / P (H ₂ ) is more preferably in the range of 0.001 to 1.50, even more preferably in the range of 0.002 to 1.20.
[0097] The average cooling rate from the maximum heating temperature is important to generate sufficient ferrite. Consequently, in the present invention, the average rate of cold
46/112 750 to 650Ό which is the temperature range in which the ferrite is generated is set to 1.0 to Ιδ, Ο'Ό / ε. When the average cooling rate from the maximum heating temperature exceeds Ιδ, Ο'Ό / ε it is possible that a sufficient amount of ferrite cannot be obtained, and the ductility deteriorates. On the other hand, when the average cooling rate is less than 1.0O / s, a sufficient amount of the hard structure cannot be obtained due to excessive generation of ferrite, generation of perlite, and / or the like, and the resistance deteriorates.
[0098] The average rate of cooling until cooling is terminated to enter the coating bath from the temperature of 650Ό is preferably 3.0 ° C / s or more. This is to obtain a hard structure with a more random crystal orientation in order to decrease the transformation temperature up to the hard structure. From this point of view, the average cooling rate is more preferably 5.0Ό / ε or more. In addition, although the upper limit of the average cooling rate is not particularly adjusted, having an average cooling rate exceeding 200O / S requires special cooling equipment, and so it is preferably 200 ° C / s.
[0099] Next, the coating step of dipping the steel sheet is performed after the annealing step in the coating bath. The composition of the coating bath consists mainly of zinc, and the effective amount of Al, which is the value obtained by subtracting the total amount of Fe from the total amount of Al in the bath, is preferably 0.01 to 0.20% by mass, more preferably 0.01 to 0.18% by mass. Particularly, when the bonding treatment is carried out, to control the bonding layer bonding procedure, the effective amount of Al in the bath is more preferably 0.07 to 0.12 mass%. In addition, when the coating layer is not bonded, the effective amount of Al in the bath can be in the range of 0.18 to 0.20% by mass.
47/112 [00100] Furthermore, when one or more elements between Pb, Sb, Si, Sn, Mg, Mn, Ni, Cr, Co, Ca, Cu, Li, Ti, Be, Bi, Sr, I, Cs , Sr, REM is the mixture (s) in the plating bath, the effect of the present invention is not impaired, and there may even be cases where they improve corrosion resistance, workability, and / or the like depending on their quantities and then are preferable.
[00101] The temperature of the coating bath is preferably 450Ό to 470-Ό. When the coating bath temperature is less than 450Ό, the coating bath viscosity increases excessively, it becomes difficult to control the thickness of the coating layer, and the appearance of the steel sheet is impaired. On the other hand, when the temperature of the coating bath exceeds 470Ό, a large amount of steam is generated making production difficult to safely, and then the temperature of the coating bath is preferably 470Ό or less.
[00102] Furthermore, in order to stabilize the temperature of the coating bath, the inlet temperature of the steel sheet in the coating bath is preferably 430Ό to 490Ό. If the temperature of the steel sheet when the steel sheet enters the coating bath is less than 430Ό, it becomes necessary to supply a large amount of heat to the coating bath to stabilize the temperature of the coating bath to 450Ό or more, and so it is practically inappropriate. On the other hand, if the temperature of the steel sheet when the steel sheet enters the coating bath is greater than 490Ό, it is necessary to introduce equipment to remove a large amount of heat from the coating bath to stabilize the temperature of the coating bath to 470Ό or less, and then it is inadequate in terms of production cost.
[00103] In the present invention, to obtain sufficiently retained austenite, before and / or after diving into the coating bath,
48/112 the steel plate is retained in the range of 300 to 470Ό, in order to make the transformation of bainite happen. This retention time in the 300 to 4670Ό range is 20 to 1000 seconds including the immersion time in the coating bath. When this coating time is less than 20 seconds, the transformation of bainite does not happen sufficiently, and the carbon concentration until the retained austenite becomes insufficient. In addition, to also increase the curing capacity in cooking, the retention time is more preferably 35 seconds or more, even more preferably 50 seconds or more. On the other hand, when the above retention time exceeds 1000 seconds, the carbon is excessively concentrated in the retained austenite, or cementite generation begins and predetermined characteristics cannot be obtained. In addition, in order to control the carbon concentration in the retained austenite to obtain high hardening capacity in cooking, the retention time is preferably 600 seconds or less, more preferably 450 seconds or less.
[00104] In addition, to micronize the diameter of the crystal grains of the retained austenite, it is effective to facilitate the nucleation of bainite and / or bainitic ferrite to cause nucleation from the respective portions of the steel sheet, in order to divide finely austenite in the base phase. For this, the deformation by bending is performed in a state in which the tensile effort is applied to the steel sheet between 300 and 470Ό, thus facilitating the nucleation of a large amount of bainite and / or bainitic ferrite. As pressure at that time, a pressure of 3 to 100 MPa is applied with the rolling direction being the axis of traction. When the loading pressure is less than 3 MPa, the effect of facilitating nucleation cannot be recognized and therefore this value is taken as a lower limit. In addition, to also facilitate nucleation to micronize the diameter of the effective crystal grain, the
Loading pressure is more preferably 5 MPa or more, even more preferably 7 MPa or more. On the other hand, when the loading pressure exceeds 100 MPa, the steel sheet can deform greatly, and thus the loading pressure is 100 MPa or less. In addition, to make the deformation of the steel sheet less, the loading pressure is more preferably 70 MPa or less, even more preferably 50 MPa or less.
[00105] The given stress and thermal history from the hot rolling step to the annealing step and the stress given during the aforementioned bainite transformation, the amount of carbon in the solid solution in the retained austenite phase can be 0.70 at 1.00%, the average grain diameter can be 2.0 pm or less in addition, and the average distance between grains can be 0.1 to 5.0 pm. In addition, the hardening coefficient at work can be 0.080 or more on average during plastic deformation of 3 to 7%.
[00106] By performing bending deformation in a state where the tensile strength of the above condition is applied, nucleation is greatly facilitated, and thus, in the present invention, bending with a bending radius of 800 mm or less is performed one or more times. On the other hand, the lower limit of the bending radius is not particularly adjusted. However, since it is difficult to bend the entire steel sheet area homogeneously with an excessively small radius, the bending radius is preferably 50 mm or more, more preferably 100 mm or more.
[00107] Furthermore, the number of folding times is one or more, and moreover it is more preferably twice or more because the higher the degree of processing, the more nucleation is facilitated. It is noted that although the upper limit on the number of processing times is not particularly adjusted, it is difficult to perform the folding 20 times or more in the retention time in that time range.
50/112 times, and then the number of times of processing is preferably 20 times or less.
[00108] In the present invention, after the aforementioned hot dip galvanizing treatment is carried out, a bonding treatment of the coating layer on the steel sheet surface can also be carried out at temperatures from 470 to 620 °. Performing such a bonding treatment, a Zn-Fe alloy formed by bonding the hot-dip galvanized layer is formed on the surface, thus obtaining a hot-dip galvanized steel sheet bonded with high resistance to corrosion prevention. .
[00109] To connect the coating layer, the temperature of the bonding treatment is 470Ό or more because the bonding does not happen sufficiently when it is less than 470Ό. In addition, when the temperature of the bond treatment exceeds 620Ό, crude cementite is generated and the resistance decreases significantly, and then 620Ό or less is the upper limit in the present invention. In addition, the temperature of the bonding treatment is more preferably 480 to 600 °, even more preferably 490 to 580 °.
[00110] Furthermore, the time of the binding treatment is not particularly limited, but it needs to be two seconds or more for the connection to proceed sufficiently, and is more preferably 5 seconds or more. On the other hand, when the bonding treatment time exceeds 200 seconds, there is a concern that an excessive bonding of the coating layer occurs, and the characteristics deteriorate. Thus, the treatment time is 200 seconds or less, preferably 100 seconds or less.
[00111] Note that although the bonding treatment is preferably carried out immediately after immersion in the coating bath, it is also possible to let it cool down to a temperature of
51/112 steel plate 150Ό or less after immersion, and then reheat to the temperature of the bonding treatment.
[00112] In addition, when the average cooling rate when cooling to 150Ό or less after bonding treatment is less than 0.5O / s, crude cementite is generated, and there is a concern that the resistance and / or the ductility deteriorate. Thus, the average cooling rate is adjusted to 0.5O / s or more, more preferably 1.0 ° C / s or more. It is noted that although the upper limit of the average cooling rate is not particularly adjusted, it is preferably 200O / s or less, more preferably õOO / s or less because having an average cooling rate exceeding 200O / S requires special equipment. cooling.
[00113] Furthermore, when the bonding treatment of the coating layer is carried out, the time for carrying out the bainite transformation process described above may be before or after the bonding treatment.
[00114] In addition, in the present invention, during cooling or after cooling, the thermal treatment can be carried out with the purpose of tempering the martensite. The reheat temperature to reheat is preferably 200 Ό or more because the quench does not happen sufficiently when it is less than 200 Ό. In addition, when the reheat temperature exceeds 520Ό, the resistance deteriorates significantly and then it is 620Ό or less, more preferably 550Ό or less.
[00115] In addition, in this configuration, to correct the shape, it is also possible to perform cold rolling with a reduction ratio of 3.00% or less on the high-strength hot-dip galvanized steel sheet or on the high-strength, hot-dip galvanized steel that is cooled to room temperature.
52/112 [00116] It is noted that the production method of the present invention is not limited to the example described above.
[00117] For example, in the present invention, a coating film consisting of phosphorus oxide and / or a compound oxide containing phosphorus can be added to the surface of the coating layer of the high-strength hot-dip galvanized steel sheet obtained by method described above. Such a coating film consisting of phosphorus oxide and / or phosphorus-containing compound oxide can function as a lubricant when the steel plate is processed, and can protect the coating layer formed on the surface of the base steel plate.
[00118] The high-strength hot-dip galvanized steel sheet and the high-strength hot-dip galvanized steel sheet excellent in mechanical cutting properties according to the present invention as described above employ a structure in which the components of the steel, the structure of the steel plate, the thickness of the decarburized layer, and the size, etc., of the oxides in the portion of the surface layer of the steel plate, etc., are defined for suitable ranges as described above. That is, because it contains a predetermined amount or more of austenite phase retained in the steel sheet structure, the work hardening capacity is increased, and with that the strength and ductility of the steel sheet can be improved, and increasing the density by limiting the amount of carbon in the solid solution in the retained austenite phase and suppressing the average diameter and grain, the mechanical cutting property when processing the steel sheet (punching work capacity) improves. In addition, by limiting the thickness of the decarburized layer and the average diameter of the grain and the average distance between grains of the oxides in the portion of the surface layer of the steel sheet, the better ability of the coating layer to adhere
53/112 ra. Therefore, while ensuring maximum tensile strength of
900 MPa or more, the high-strength hot-dip galvanized steel sheet and the high-strength hot-dip galvanized steel sheet can be obtained capable of obtaining excellent ductility and mechanical cutting properties.
[00119] In addition, the production method of the high-strength hot-dip galvanized steel sheet and the high-strength hot-dip galvanized steel sheet in accordance with the present invention employs a method that adjusts the steel components to a suitable range, and limits the conditions of hot rolling, cold rolling and annealing after rolling to certain ranges. Thus, the ratio of the austenite phase retained in the steel sheet structure can be controlled to a predetermined ratio or more, and the average grain diameter and the average distance between grains can be limited to a predetermined range while limiting the amount of carbon in the solid solution in the retained austenite phase, and thus it is possible to improve the strength and ductility as well as the mechanical cutting property of the steel sheet. In addition, since the thickness of the decarburized layer, and the average grain diameter and the average density of the oxides in the surface layer portion of the steel sheet can be limited to a predetermined range, it is possible to improve the adhesion capacity of the steel plate. coating layer. Therefore, while ensuring the maximum tensile strength of 900 MPa or more as described above, it is possible to produce the high strength hot dip galvanized steel sheet and the high strength bonded hot dip galvanized steel sheet capable of obtain excellent ductility and mechanical cutting property.
[00120] Therefore, applying the high-strength hot-dip galvanized steel sheet and the high-strength hot-dip galvanized steel sheet excellent in property
54/112 mechanical cutting, and the production method of the present invention in the automotive field in particular, merits such as improved safety accompanied by increased strength of the vehicle chassis, improved workability for processing an element, and the like can be used sufficiently, and their social contributions are immeasurable.
EXAMPLE [00121] Hereinafter, the present invention will be described more specifically using examples of high-strength hot-dip galvanized steel sheet and high-strength hot-dip galvanized steel sheet excellent in mechanical cutting properties, and its production method according to the present invention. However, the present invention is of course not limited to the examples below and can be implemented by appropriately adding changes within the range compatible with the essence described above and below, and they are all included in the technical scope of the present invention.
Production of steel plates [00122] Initially plates with the chemical components illustrated in Table 1 below were obtained by controlling the deoxidation and desulfurization and the chemical components of the molten steel in the steel production stage. Then, after casting, they were immediately subjected to hot rolling, cold rolling, winding, pickling under the conditions illustrated in Tables 2 to 4 below and, in addition, subjected to cold rolling. Subsequently, the cold rolled steel sheets obtained were passed through a line of continuous annealing and galvanizing under the conditions illustrated in Tables 5 to 8 below, in order to produce hot dip galvanized steel sheets of experimental examples 1 to 128. In addition, in part of these experimental examples 1 to 128,
55/112 the bonding treatment of the cladding layer was carried out under the conditions illustrated in Tables 5 to 8, thus producing bonded hot dip galvanized steel sheets (GA). For steel sheets other than these, the bonding treatment was not carried out, or the treatment temperature was adjusted to less than 470Ό, thus producing hot-dip galvanized steel sheets (Gl) whose coating layer is not bonded.
Table 1
No. of Chemical Component (% by mass)
Ç Si Mn P s Al N O You Nb V Cr Ni THE 0.117 1.39 1.57 0.0160 0.0015 0.033 0.0045 0.0008B 0.238 0.83 1.51 0.0135 0.0018 0.039 0.0037 0.0014Ç 0.201 1.67 1.92 0.0096 0.0023 0.056 0.0029 0.0010D 0.339 0.29 2.12 0.0064 0.0032 0.511 0.0030 0.0034AND 0.084 0.77 2.71 0.0107 0.0005 0.048 0.0045 0.0008F 0.089 0.95 1.55 0.0121 0.0005 0.023 0.0069 0.0017 0.072 G 0.279 0.68 1.35 0.0094 0.0050 0.258 0.0014 0.00160.031 H 0.130 0.06 1.84 0.0064 0.0040 1,066 0.0031 0.0011I 0.148 1.69 1.11 0.0122 0.0017 0.027 0.0041 0.0018 0.43J 0.226 0.47 2.93 0.0068 0.0044 0.067 0.0069 0.0023 0.44 K 0.153 1.49 1.69 0.0051 0.0002 0.022 0.0007 0.0011L 0.191 1.33 2.29 0.0171 0.0036 0.038 0.0030 0.0008M 0.179 1.28 1.74 0.0088 0.0019 0.006 0.0025 0.0005N 0.106 0.61 1.45 0.0211 0.0006 0.007 0.0025 0.0006 0.80 O 0.169 0.14 1.33 0.0120 0.0038 0.418 0.0051 0.0004 0.73P 0.160 0.71 1.88 0.0068 0.0082 0.060 0.0013 0.0012Q 0.240 0.81 1.28 0.0084 0.0019 0.012 0.0054 0.0016R 0.214 1.94 2.68 0.0186 0.0022 0.034 0.0048 0.0009s 0.262 0.58 2.47 0.0061 0.0060 0.069 0.0038 0.0023 0.028
56/112
Table 1 -continuation-
No. Chemical component (% by mass) Grades Ass Mo B W Here Ce Mg Zr There REM THE Example B Example Ç Example D Example AND Example F Example G Example H0.09 0.0007 Example I Example J 0.19Example K 0.0021 Example L 0.37Example M 0.0031 0.0010 Example N Example O0.04 Example P0.0046 Example Q 0.0022 Example R 0.0029 Example s 0.0025 Example
57/112
Table 1 -continuationN ° Chemical component (% by mass)
T Ç0.240 Si1.29 Mn0.84 P0.0092 s0.0003 Al0.014 N0.0033 O0.0008 You Nb V Cr1.07 Ni u 0.152 0.49 1.50 0.0074 0.0024 0.250 0.0030 0.0009 0.014 0.008 V 0.239 1.79 1.50 0.0119 0.0048 0.048 0.0042 0.0009 0.115 w 0.098 0.97 2.30 0.0080 0.0011 0.105 0.0023 0.0045X 0.201 1.11 2.63 0.0207 0.0010 0.030 0.0027 0.0009 0.007 0.024 Y 0.134 1.15 1.73 0.0121 0.0040 0.024 0.0021 0.0013z 0.220 1.57 1.32 0.0078 0.0011 0.068 0.0027 0.0014AA 0.109 0.32 2.45 0.0081 0.0003 1,361 0.0063 0.0009AB 0.208 1.65 1.97 0.0092 0.0048 0.012 0.0050 0.0018B.C 0.162 1.30 1.13 0.0081 0.0037 0.023 0.0015 0.0019 0.76 AD 0.155 1.27 2.80 0.0052 0.0048 0.054 0.0031 0.0007AE 0.062 1.07 1.94 0.0103 0.0038 0.017 0.0041 0.0010AF 0.493 1.07 1.95 0.0081 0.0041 0.019 0.0038 0.0015AG 0.149 1.06 0.49 0.0099 0.0039 0.023 0.0045 0.0013AH 0.190 2.75 2.39 0.012 0.0035 .034 0.0039 0.0012Al 0.151 0.00 2.18 0.008 0.0028 0.520 0.0048 0.0011AJ 0.180 0.48 4.02 0.009 0.0024 0.074 0.0031 0.0017AK 0.130 0.98 2.47 0.018 0.0027 2.63 0.0044 0.0021
58/112
Table 1 -continuation-
No. Chemical component (% by mass) Grades Ass Mo B W Here0.0012 Ce Mg Zr There REM T Example u 0.0035 0.0028 Example V Example w 0.0034Example X Example Y0.0013 Example z 0.0017Example AA0.23 Example AB 0.30 Example B.C 0.51Example AD Example AE Comparative Example AF Comparative Example AG Comparative Example AH Comparative Example Al Comparative Example AJ Comparative Example AK Comparative Example
59/112
Table 2
Experimental Example Steel composition Hot delamination step Cold rolling stage Grades Plate heating temperature Lamination termination temperature Average cooling rate Cooling end temperature Elapsed time up to 4000 Reduction ratio% Ό Ό The Ό Time 1 THE 1240 886 33 605 8.3 50 Example 2 THE 1240 917 23 625 5.9 42 Example 3 THE 1210 885 28 580 5.0 53 Example 4 THE 1215 885 29 595 4.1 43 Comparative example 5 B 1235 887 34 602 2.9 52 Example 6 B 1215 888 66 525 3.1 66 Example 7 B 1210 925 57 579 8.1 40 Example 8 B 1265 928 28 578 4.2 50 Comparative example 9 Ç 1205 914 52 574 7.4 45 Example 10 Ç 1245 859 16 640 7.4 55 Example 11 Ç 1240 873 45 619 6.8 43 Example 12 Ç 1240 915 54 612 9.4 63 Comparative example 13 D 1230 908 41 599 10.6 46 Example 14 D 1270 937 55 583 8.0 58 Example 15 D 1220 922 35 608 7.3 54 Example 16 D 1045 885 48 582 5.8 63 Comparative example 17 AND 1235 896 38 623 11.3 58 Example 18 AND 1195 864 17 627 3.0 60 Example 19 AND 1275 898 30 598 7.1 60 Example 20 AND 1235 905 5 601 9.8 44 Comparative example 21 F 1280 905 34 594 7.5 52 Example 22 F 1210 870 27 560 3.3 50 Example 23 F 1255 926 51 592 3.8 44 Example
60/112
Experimental Example24 Steel compositionF Hot delamination step Cold rolling stage Notes Comparative example Plate heating temperature Lamination termination temperature Average cooling rate Cooling end temperature Elapsed time up to 4000 Reduction ratio%60 Ό Ό The Ό Time 1240 927 43 609 4.9 25 G 1200 908 42 588 4.6 53 Example 26 G 1240 919 32 554 2.6 67 Example 27 G 1220 910 35 593 6.4 35 Example 28 G 1200 922 38 605 9.7 41 Comparative example 29 H 1250 886 47 571 5.4 50 Example 30 H 1270 933 51 560 8.3 71 Example 31 H 1205 893 27 607 5.0 35 Example 32 H 1210 882 21 609 6.0 52 Example 33 I 1225 885 28 560 7.2 50 Example 34 I 1205 913 26 609 7.0 44 Example 35 I 1240 878 47 557 4.4 31 Example 36 I 1245 904 24 613 5.5 39 Comparative example 37 J 1260 887 28 597 6.1 44 Example 38 J 1190 906 55 606 2.5 53 Example 39 J 1235 854 49 574 3.7 43 Example 40 J 1185 897 26 568 4.5 43 Comparative example
61/112
Table 3
Experimental Example Steel composition Hot rolling step Cold rolling stage Grades Plate heating temperature Lamination termination temperature Average cooling rate Cooling end temperature Elapsed time up to 400Ό Reduction ratio% Ό Ό The Ό Time 41 K 1220 923 54 578 6.4 41 Example 42 K 1200 941 58 571 5.4 34 Example 43 K 1200 888 31 613 6.5 38 Example 44 K 1210 907 34 434 1.8 41 Comparative example 45 L 1210 880 39 567 5.0 50 Example 46 L 1280 878 36 635 7.1 38 Example 47 L 1265 882 33 593 4.3 52 Example 48 L 1280 924 26 583 7.1 65 Comparative example 49 M 1280 887 31 564 3.6 41 Example 50 M 1270 895 39 580 3.9 50 Example 51 M 1255 890 33 600 6.1 35 Example 52 M 1270 887 28 568 4.9 53 Comparative example 53 N 1280 881 39 610 5.8 52 Example 54 N 1185 887 41 533 10.3 53 Example 55 N 1200 912 41 590 6.8 56 Example 56 N 1235 888 27 585 7.6 43 Comparative example 57 O 1205 896 42 593 5.3 40 Example 58 O 1210 891 27 601 1.9 37 Example 59 O 1275 887 49 598 5.2 72 Example 60 O 1250 894 28 599 7.4 52 Comparative example 61 P 1225 905 53 602 4.1 53 Example 62 P 1245 903 32 561 7.0 63 Example
62/112
Table 3 -continuation-
Experimental Example Steel composition Hot rolling step Cold rolling stage Grades Plate heating temperature Lamination termination temperature Average cooling rate Cooling end temperature Elapsed time up to 400Ό Reduction ratio% Ό Ό The Ό Time 63 P 1210 902 54 573 8.3 47 Example 64 P 1190 1010 57 628 4.8 37 Example 65 Q 1270 913 52 614 9.0 50 Example 66 Q 1220 906 34 554 7.0 58 Example 67 Q 1280 911 34 517 1.8 40 Example 68 Q 1275 912 22 628 7.4 52 Example 69 R 1210 892 41 599 5.0 38 Example 70 R 1280 892 29 607 4.5 42 Example 71 R 1220 924 27 569 1.7 60 Example 72 R 1265 889 50 597 5.7 44 Example 73 s 1225 915 33 619 10.6 61 Example 74 s 1265 922 49 572 3.2 43 Example 75 s 1270 934 24 641 6.9 53 Example 76 s 1245 928 34 581 5.3 61 Example 77 T 1185 901 45 561 3.4 56 Example 78 T 1260 882 45 572 5.7 50 Example 79 T 1225 924 42 555 3.4 53 Example 80 T 1205 915 16 712 7.0 46 Example
63/112
Table 4
Experimental Example Steel composition Hot lamination stage cold rolling step Grades Plate heating temperature Lamination termination temperature Average cooling rate Cooling end temperature Elapsed time up to 400Ό Reduction ratio Ό Ό The Ό s % 81 U 1265 875 42 579 5.3 52 Example 82 U 1235 898 35 540 4.4 68 Example 83 U 1215 897 39 600 8.6 41 Example 84 U 1245 894 42 598 4.3 34 Comparative example 85 V 1265 899 31 558 3.7 33 Example 86 V 1220 910 52 540 5.2 55 Example 87 V 1265 863 32 561 7.2 50 Example 88 V 1240 892 43 563 3.3 53 Comparative example 89 W 1225 894 31 626 5.5 46 Example 90 W 1240 901 30 568 3.7 62 Example 91 W 1220 915 48 539 3.3 40 Example 92 W 1235 883 41 574 6.7 53 Comparative example 93 X 1195 922 31 623 5.5 50 Example 94 X 1265 905 35 595 6.3 61 Example 95 X 1230 920 45 524 2.5 35 Example 96 X 1210 912 40 573 3.8 50 Comparative example 97 Y 1230 893 46 583 4.2 46 Example 98 Y 1275 943 48 558 3.6 52 Example 99 Y 1275 906 37 595 5.0 36 Example 100 Y 1220 915 25 604 11.2 34 Comparative example 101 z 1230 895 25 595 5.7 37 Example 102 z 1270 923 31 596 7.0 41 Example 103 z 1235 892 24 581 5.4 62 Example 104 z 1205 924 52 578 9.7 20 Comparative example 105 AA 1275 938 30 556 5.4 56 Example 106 AA 1270 927 35 554 4.7 63 Example 107 AA 1280 879 36 620 4.1 41 Example 108 AA 1180 908 41 617 5.1 61 Comparative example
64/112
Table 4 -continuation-
Experimental Example 109 Composition of AB steel Hot lamination stage cold rolling step Example Notes Plate heating temperature Lamination termination temperature Average cooling rate Cooling end temperature Elapsed time until 40010 Reduction ratio Ό1215 Ό887 The47 Ό625 s9.6 %40 110 AB 1210 919 54 572 6.3 46 Example 111 AB 1235 886 39 593 9.4 40 Example 112 AB 1260 923 31 525 0J3 35 Example 113 B.C 1245 911 38 594 4.8 50 Example 114 B.C 1260 873 23 571 8.2 62 Example 115 B.C 1210 896 53 584 5.9 54 Example 116 B.C 1260 917 31 574 5.2 82 Example 117 AD 1205 907 33 603 6.0 61 Example 118 AD 1240 884 39 580 7.3 53 Example 119 AD 1260 915 38 592 5.9 52 Example 120 AD 1225 880 23 607 6.8 42 Example 121 AE 1230 905 38 606 5.5 55 Example 122 AF 1225 896 39 605 7.8 55 Example 123 AG 1230 906 41 600 6.6 55 Example 124 THE 1195 901 22 599 8.3 53 Example 125 AH 1220 920 20 609 6.3Example 126 Al 1240 916 39 596 7.7 73 Example 127 AJ EXPERIENCEINTERROMPITYFRATURANANAPLACA Example 128 AK 1225 906 20 619 4.1 53 Example
65/112
Table 5
Experimental example Steel composition Steel type Annealing step - Coating step Heating step First cooling step Bainite transformation process Heating rate at 600 to 750 = 0 Heating temperature Cooling rate at 750 to 500 = 0 Cooling rate from 600 = 0 Retention time at 300 to 470 = 0 Charge pressure Folding radius Number of processing times C / s Ό C / s C / s s MPa mm times 1 THE Gl 4.7 827 1.5 6.2 56 8 200 4 2 THE GA 7.9 815 12.8 106.7 44 6 200 4 3 THE GA 1.5 830 6.2 14.8 143 24 200 4 4 THE Gl 6.8 805 24.5 4.2 75 8 200 4 5 B Gl 3.5 828 2.8 59.9 56 9 450 3 6 B GA 3.2 799 11.0 4.0 98 44 450 3 7 B GA 1.1 785 6.7 4.0 48 18 450 3 8 B Gl 8.6 768 6.5 5.2 1376 8 450 3 9 Ç Gl 4.7 847 1.7 3.8 77 23 450 3 10 Ç GA 7.3 862 1.9 6.0 480 25 450 3 11 ç GA 13.4 853 2.1 22.2 80 6 450 3 12 ç Gl 4.2 830 2.8 4.9 81 10 450 3 13 D Gl 3.6 780 3.0 4.8 58 25 200 2 14 D GA 5.3 813 5.7 3.8 71 9 200 2 15 D GA 8.1 781 3.8 74.7 114 10 200 2 16 D Gl 1.7 764 7.2 6.7 80 25 200 2 17 AND GA 8.9 810 4.6 4.2 58 16 500 2 18 AND Gl 1.1 827 2.1 96.0 80 10 200 8 19 AND GA 3.1 793 3.8 4.7 58 14 500 2
66/112
Table 5 -continuation-
Experimental example Steel composition Steel type Annealing step - Coating step Note preheating zone reduction zone Bonding oven coating zone second cooling step tempering step cold rolling Air ratio P (H2O)0 / P (H2) Effective amount of Al Coating bath temperature steel sheet inlet temperature connection temperature treatment time Cooling rate Tempering temperature reduction ratio % in large scale ç ç ç s C / s Ό % 1 THE Gl 1, the 0.033 0.08 458 468 2.8 Example 2 THE GA 0.9 0.035 0.11 457 453 492 19 1.6 Example 3 THE GA 1.0 0.033 0.09 469 454 486 11 4.6 Example 4 THE Gl 1.0 0.087 0.11 461 459 5.2 Exemplary example 5 B Gl 1.2 0.014 0.09 466 474 2.3 Example 6 B GA 0.9 0.010 0.08 462 464 533 24 4.5 Example 7 B GA 1.1 0.891 0.10 368 465 494 30 1.8 350Example 8 B Gl 1.0 0.035 0.09 454 447 3.3 Exemplary example 9 Ç Gl 0.9 0.056 0.14 462 458 5.1 Example 10 Ç GA 1.0 0.030 0.10 453 481 507 12 2.10.45 Example 11 Ç GA 0.0 0.123 0.10 461 456 522 8 2.9 Example 12 Ç Gl 1.0 0.0000 0.08 461 448 2.8 Exemplary example 13 D Gl 1.1 0.054 0.11 459 451 3.0 Example 14 D GA 1.0 0.004 0.08 467 454 503 13 4.7 Example 15 D GA 1.1 0.144 0.07 459 467 497 46 2.01.10 Example 16 D Gl 0.8 0.134 0.10 467 470 3.1 Exemplary example 17 AND GA 1.1 0.020 0.11 464 455 548 16 4.0 Example 18 AND Gl 0.9 0.141 0.10 456 450 0.8 Example 19 AND GA 0.8 0.057 0.08 460 458 529 7 3.1 Example
67/112
Table 5 -continuation-
Experimental example Steel composition Steel type Re-baking step -Lining step Warming-up stage First cooling step Debainite transformation process Heating rate at 600 to 750 = 0 Heating temperature Cooling rate a750 to 500 = 0 Cooling rate from 6000 Retention time at 300 to 4700 Charge pressure Folding radius Number of processing times Ç / s O The The s MPa mm times 20 AND Gl 9.5 792 9.1 3.8 74 16 500 2 21 F GA 3.9 874 2.8 5.4 61 19 450 2 22 F Gl 4.1 804 3.4 70.2 70 9 450 2 23 F GA 0.7 830 5.8 7.4 227 4 450 2 24 F Gl 28.1 805 9.2 7.5 82 20 450 2 25 G Gl 6.0 799 3.7 5.6 72 20 450 3 26 G Gl 4.6 756 5.4 50.3 228 14 450 3 27 G GA 0.9 800 2.4 7.2 52 13 700 3 28 G Gl 1.9 779 5.5 4.0 63 18 450 3 29 H GA 7.4 844 2.4 5.6 68 9 450 2 30 H Gl 5.3 846 6.8 6.7 268 24 85 2 31 H GA 7.7 834 5.7 19.5 96 16 450 2 32 H Gl 10.0 837 9.3 6.0 55 11 450 2 33 I Gl 9.6 879 2.1 38.4 62 11 450 3 34 I GA 3.8 966 1.7 55.0 36 42 450 3 35 I GA 8.6 821 7.2 5.5 55 8 450 3 36 I Gl 8.8 734 4.0 6.5 81 21 450 3 37 J Gl 4.3 798 8.1 6.3 72 13 450 3 38 J GA 2.0 812 2.1 7.0 83 13 450 3 39 J GA 3.8 829 6.3 60.6 668 7 450 3 40 J Gl 8.5 775 5.3 5.7 77 24 450 3
68/112
Table 5 -continuation-
Experimental example Steel composition Steel type Annealing step - Coating step Note preheating zone reduction zone Coating zone second cooling step tempering step cold rolling Air ratio P (H2O) 0 / P (H2) Effective amount of Al Coating bath temperature steel sheet inlet temperature connection temperature treatment time Cooling rate Tempering temperature reduction ratio % in large scale ç ç ç s C / s Ό % 20 AND Gl 0.9 0.194 0.09 468 439 3.0 Exemplary example 21 F GA 0.8 0.074 0.10 465 477 506 24 5.1 Example 22 F Gl 1.1 0.125 0.08 468 456 1.4 Example 23 F GA 0.9 0.091 0.10 463 472 519 12 4.3 Example 24 F Gl 0.9 0.043 0.08 464 482 1.4 Exemplary example 25 G Gl 1.0 0.070 0.09 455 454 3.0 Example 26 G Gl 0.7 1.30 0.08 451 453 4.4 380Example 27 G GA 1.1 0.029 0.08 454 446 555 14 3.5 Example 28 G Gl 0.4 0.251 0.11 468 481 2.8 Exemplary example 29 H GA 0.8 0.194 0.08 458 467 509 15 3.7 Example 30 H Gl 1.1 0.208 0.10 453 455 1.4 Example 31 H GA 0.8 0.041 0.10 467 460 494 98 2.4 Example 32 H Gl 0.9 0.039 0.08 465 457 3.5 410 0.15 Example 33 I Gl 1.0 0.162 0.10 454 459 2.4 Example 34 I GA 1.2 0.318 0.11 466 471 491 17 1.8 Example 35 I GA 0.8 0.016 0.12 465 473 481 30 1.1 Example 36 I Gl 1.1 0.218 0.10 464 458 3.3 Exemplary example 37 J Gl 0.8 0.070 0.09 462 479 2.3 Example 38 J GA 1.1 0.213 0.08 453 472 593 4 5.2 Example 39 J GA 1.0 0.537 0.09 460 458 531 19 4.5 Example 40 J Gl 1.1 0.052 0.24 463 460 1.9 Exemplary example
69/112
Table 6
Experimental example Steel composition Type ofsteel Re-baking step -Lining step Warming-up stage First cooling step Debainite transformation process preheating zone reduction zone Heating rate at600 to 750Ό Heating temperature Cooling rate a750 to 500Ό Cooling rate from 600Ό Retention time at 300 to 470Ό Charge pressure Folding radius Number of processing times Air ratio P (H2O) 0 /P (H2) C / s ç C / s C / s s MPa mm times 41 K Gl 10.8 769 5.4 7.5 63 14 200 5 1.1 0.052 42 K Gl 4.4 792 6.4 64.5 108 35 200 5 1.0 0.114 43 K GA 3.5 784 1.3 5.8 75 8 200 5 1.0 0.144 44 K Gl 1.1 801 8.9 4.0 68 22 200 5 0.9 0.052 45 L Gl 2.6 805 2.4 64.7 59 23 200 2 1.0 0.0004 46 L Gl 9.2 822 7.9 4.0 113 22 200 2 0.9 0.038 47 L GA 5.5 820 3.1 7.5 192 17 200 2 1.0 0.039 48 L GA 3.3 795 2.8 6.1 60 13 200 2 1.1 0.154 49 M Gl 1.6 831 2.1 5.8 67 20 500 3 0.9 0.229 50 M Gl 6.5 924 2.2 43.7 250 60 500 3 0.7 0.034 51 M GA 16.4 845 9.2 6.2 56 19 500 3 1.1 0.023 52 M Gl 2.6 830 0.3 6.5 65 12 500 3 1.0 0.029 53 N Gl 3.9 826 4.8 6.8 62 10 300 2 0.9 0.033 54 N Gl 4.3 833 2.6 21.7 73 22 300 2 0.9 0.288 55 N GA 5.7 800 7.1 3.8 133 6 300 2 1.2 0.154 56 N GA 8.3 813 5.4 6.9 74 13 300 2 0.9 0.024 57 0 Gl 1.3 832 1.7 5.8 81 13 500 3 0.8 0.043 58 0 GA 2.6 886 5.6 4.8 195 19 500 1 1.1 0.083 59 0 GA 7.3 765 11.4 7.1 105 18 500 3 1.0 0.038 60 0 Gl 3.7 816 6.5 5.4 79 10 500 3 0.8 0.251 61 P GA 4.1 768 6.0 6.2 77 12 450 2 0.8 0.024
70/112
Table 6 -continuation-
Experimental example Steel composition Type ofsteel Re-baking step -Lining step Note Zonadercoatingconnection oven second cooling step stopper stage cold rolling effective amount of Al Coating bath temperature steel sheet inlet temperature connection temperature treatment time Cooling rate temper temperature reduction ratio % in large scale ç ç ç s C / s Ό % 41 K Gl 0.08 456 450 4.7 Example 42 K Gl 0.11 459 443 4.2 Example 43 K GA 0.08 461 469 496 23 1.5 Example 44 K Gl 0.10 457 468 3.6 Exemplary example 45 L Gl 0.10 465 472 1.3 Example 46 L Gl 0.09 453 461 4.51.00 Example 47 L GA 0.11 462 457 537 17 1.9 Example 48 L GA 0.10 457 461 519 340 4.4 Exemplary example 49 M Gl 0.07 466 448 2.2 Example 50 M Gl 0.08 467 481 4.8 Example 51 M GA 0.08 463 456 560 10 5.2 Example 52 M Gl 0.09 467 457 3.7 Exemplary example 53 N Gl 0.09 455 472 3.1 Example 54 N Gl 0.10 458 487 8.6 Example 55 N GA 0.11 468 467 519 12 4.6 Example 56 N GA 0.09 466 459 492 1 2.8 Exemplary example 57 0 Gl 0.08 459 471 1.9 Example 58 0 GA 0.10 456 460 603 5 2.3 Example 59 0 GA 0.11 467 456 555 18 4.2 Example 60 0 Gl 0.11 460 459 0J. Exemplary example 61 P GA 0.10 455 465 574 10 3.4 Example
71/112
Table 6 -continuation-
Experimental example Steel composition Type ofsteel Re-baking step -Lining step Warming-up stage First cooling step Debainite transformation process preheating zone reduction zone Heating rate at600 to 750Ό Heating temperature Cooling rate a750 to 500Ό Cooling rate from 600Ό Retention time at 300 to 470Ό Charge pressure Folding radius Number of processing times Air ratio P (H2O) 0 /P (H2) C / s ç C / s C / s s MPa mm times 62 P Gl 4.3 822 3.5 34.9 183 11 700 2 0.9 0.244 63 P GA 11.1 868 1.4 7.3 70 23 450 2 0.8 0.072 64 P Gl 8.4 794 8.5 5.8 74 11 450 2 0.9 0.218 65 Q GA 2.4 801 6.0 7.4 59 17 200 2 0.8 0.005 66 Q Gl 7.0 776 1.8 42.6 223 76 200 2 1.1 0.044 67 Q GA 10.3 829 10.9 25.4 345 10 200 2 1.0 0.046 68 Q Gl 5.0 774 9.4 6.1 76 19 200 2 0.9 2.41 69 R Gl 5.0 812 2.5 20.5 57 11 200 2 1.1 0.144 70 R GA 5.2 845 1.6 4.7 59 14 200 2 1.1 0.190 71 R GA 8.6 810 6.3 48.6 407 8 200 2 0.7 0.053 72 R GA 7.3 781 10.2 6.6 78 23 200 2 1.0 0.194 73 s GA 1.5 773 2.9 6.0 82 20 350 3 1.1 0.251 74 s Gl 2.6 774 1.1 72.3 310 19 350 3 1.0 0.154 75 s GA 0.7 754 2.0 7.1 58 20 350 3 0.9 0.154 76 s Gl 5.6 777 5.6 6.2 77 140 1.1 0.074 77 T Gl 3.6 769 10.0 6.0 78 17 500 2 0.7 0.141 78 T Gl 11.0 764 3.6 5.5 78 26 700 2 0.9 0.048 79 T GA 4.4 773 3.0 21.2 146 10 500 2 0.9 0.134 80 T Gl 9.1 804 4.2 6.1 64 23 500 2 1.0 0.141
72/112
Table 6 -continuation-
Experimental example Steel composition Type ofsteel Re-baking step -Lining step Note Zonadercoatingconnection oven second cooling step stopper stage cold rolling effective amount of Al Coating bath temperature steel sheet inlet temperature connection temperature treatment time Cooling rate temper temperature reduction ratio % in large scale ç ç ç s C / s Ό % 62 P Gl 0.10 467 462 3.0 Example 63 P GA 0.10 467 469 549 23 2.2 Example 64 P Gl 0.09 467 466 4.6 Exemplary example 65 Q GA 0.13 462 478 549 10 5.0 Example 66 Q Gl 0.09 452 471 1.5 Example 67 Q GA 0.08 464 470 492 28 4.0 Example 68 Q Gl 0.11 453 447 2.8 Exemplary example 69 R Gl 0.11 467 478 2.4 Example 70 R GA 0.08 462 465 472 102 1.8 Example 71 R GA 0.12 461 456 493 39 3.6 Example 72 R GA 0.10 462 452 645 13 2.9 Exemplary example 73 s GA 0.10 453 462 507 12 3.0 Example 74 s Gl 0.09 455 475 4.3 Example 75 s GA 0.09 453 453 511 17 2.0 270.00Example 76 s Gl 0.10 457 469 4.1 Exemplary example 77 T Gl 0.10 461 469 4.3 Example 78 T Gl 0.09 468 482 0.9 Example 79 T GA 0.10 467 462 506 15 2.7 Example 80 T Gl 0.11 458 483 2.0 Exemplary example
73/112
Table 7
Experimental example Steel composition Type ofsteel Re-baking step -Lining step Heating step First step cooling Bainite transformation process preheating zone Heating ratecement at 6008 75013 Temperatureheating Cooling rate at 750 to 500Ό Cooling rate from 600Ό Time toretention at 300 8 47013 Charge pressure Folding radius Number of processing times Air ratio C / s ç C / s C / s s MPa mm times 81 U G 2.2 772 10.5 4.7 69 21 450 4 1.1 82 U Gl 1.2 763 4.1 117.5 47 8 450 4 0.8 83 U GA 6.5 794 6.2 6.2 87 33 450 4 1.2 84 U Gl 1.3 816 7.3 4.1 58 23 450 4 18 85 V Gl 10.4 801 6.9 6.9 64 17 450 3 0.8 86 V Gl 3.4 826 1.4 5.4 70 16 450 3 0.9 87 V GA 1.6 881 1.5 3.8 44 19 450 3 0.8 88 V Gl 7.8 781 2.9 4.6 60 14 1200 3 0.9 89 W Gl 6.2 811 3.4 3.8 75 16 450 2 0.9 90 W GA 10.9 848 6.1 7.2 43 8 85 2 1.0 91 W GA 9.7 794 4.2 5.6 306 17 450 2 1.0 92 W GA 1.4 815 8J. 4.9 1138 16 450 2 0.8 93 X Gl 6.0 827 10.1 14.8 54 19 450 3 0.9 94 X Gl 6.6 824 2.4 5.6 288 14 450 1 1.1 95 X GA 1.5 791 6.7 5.4 70 10 450 3 1.0 96 X Gl 4.5 811 11.0 4.4 11 11 450 3 1.1 97 Y Gl 10.3 835 6.0 72.0 76 21 450 2 0.9 98 Y Gl 6.5 905 4.7 4.2 48 21 150 2 1.1 99 Y GA 7.2 766 6.7 54.2 69 13 450 2 0.9 100 Y Gl 5.8 794 3.2 4.5 58 0 450 2 0.9 101 z Gl 6.9 801 1.7 5.2 79 7 450 3 1.0 102 z Gl 2.6 813 6.6 4.2 93 17 450 3 0.9
74/112
Table 7 -continuation-
Experimental example Steel composition Steel type Annealing step - Coating step Note Reduction zone Coating zone link oven second cooling stepCooling rate tempering step tempering temperature cold rolling P (H2O) 0 /P (H2) Effective amount of Al Coating bath temperature steel sheet inlet temperature connection temperature treatment time reduction ratio % in large scale ç ç ç s C / s Ό % 81 U G 0.001 0.11 458 435 2.0 Example 82 U Gl 0.128 0.11 461 461 4.8 Example 83 U GA 0.616 0.09 464 462 510 17 2.1 Example 84 U Gl 0.070 0.10 466 470 3.9 Exemplary example 85 V Gl 0.114 0.11 461 456 4.2 Example 86 V Gl 0.040 0.08 455 479 2.7 450Example 87 V GA 0.077 0.09 458 448 493 27 5.0 Example 88 V Gl 0.097 0.09 461 461 5.0 Exemplary example 89 W Gl 0.151 0.08 455 463 2.4 Example 90 W GA 0.158 0.04 452 432 546 9 3.3 Example 91 W GA 0.120 0.08 458 453 530 32 1.9 Example 92 W GA 0.074 0.08 464 448 588 4 1.5 Exemplary example 93 X Gl 0.057 0.08 468 460 1.3 Example 94 X Gl 1.02 0.10 453 462 5.0 Example 95 X GA 0.117 0.09 469 443 501 8 3.3 Example 96 X Gl 0.158 0.10 462 449 1.7 Exemplary example 97 Y Gl 0.233 0.09 462 476 4.3 Example 98 Y Gl 0.030 0.06 459 452 5.2 Example 99 Y GA 0.131 0.09 463 451 505 10 2A Example 100 Y Gl 0.074 0.11 465 457 2.8 Exemplary example 101 z Gl 0.097 0.09 462 465 4.3 Example 102 z Gl 0.026 0.17 460 455 10.30.33 Example
75/112
Table 7 -continuation-
Experimental example 103 Steel compositionZ Type ofsteelGA Re-baking step -Lining step Heating step First step cooling Bainite transformation process preheating zone Heating rate at 600 to 750Ό Temperatureheating Cooling rate at 750 to 500Ό Cooling rate from 600Ό Retention time at 300 to 470Ό Charge pressure Folding radius Number of processing times Air ratio C / s2.7 ç829 C / s3.5 C / s23.8 s164 MPa25 mm85 times3 1.2 104 Z Gl 6.9 784 8.9 4.7 64 12 450 3 0.8 105 AA Gl 9.6 855 2.2 6.6 89 16 250 3 0.8 106 AA Gl 6.5 870 6.6 4.2 62 13 250 3 0.9 107 AA GA 6.8 833 3.6 6.9 47 13 250 3 1.1 108 AA Gl 9.9 834 7.0 14 76 17 250 3 0.9 109 AB Gl 0.9 827 3.2 4.8 61 14 250 2 0.9 110 AB Gl 8.3 771 2.1 19.5 170 4 250 1 0.9 111 AB GA 2.7 792 2.0 22.4 40 20 250 2 0.9 112 AB Gl 9.9 832 9.2 5.9 67 14 250 2 0.8 113 THE Gl 4.7 770 1.9 4.7 71 18 500 2 0.9 114 B.C GA 7.3 797 8.2 44.3 118 10 500 2 0.8 115 B.C GA 5.9 777 5.1 7.5 70 11 500 2 1.0 116 B.CEXPERIENCEINTERROMPITYVICE FRACTURE OF STEEL DUCAPA DURING COLD ALAMINATION 117 AD GA 5.4 828 9.3 6.2 59 15 450 4 0.8 118 AD Gl 0.9 782 2.2 5.5 43 10 450 4 0.7 119 AD GA 2.7 788 1.6 20.9 136 15 450 4 0.8 120 AD Gl 3.0 798 7.2 6.2 66 25 450 4 1.0
76/112
Table 7 -continuation-
Experimental example Steel composition Steel type Annealing step - Coating step Note Reduction zone Coating zone link oven second cooling step tempering step cold rolling P (H2O) 0 /P (H2) Effective amount of Al Coating bath temperature steel sheet inlet temperature connection temperature treatment time Cooling rate temper temperature reduction ratio % in pasta ç ç ç s C / s Ό % 103 Z GA 0.002 0.08 460 443 497 24 2.1 Example 104 Z Gl 0.023 0.11 459 474 4.1 Exemplary example 105 AA Gl 0.204 0.09 468 473 3.0 Example 106 AA Gl 0.109 0.07 455 455 1.9 Example 107 AA GA 0.089 0.11 466 460 498 40 1.6 Example 108 AA Gl 0.107 0.08 458 478 4.0 Exemplary example 109 AB Gl 0.022 0.10 460 451 3.5 Example 110 AB Gl 0.190 0.08 458 459 2.3 Example 111 AB GA 0.006 0.07 458 451 505 18 1.0 Example 112 AB Gl 0.030 0.08 462 460 2.5 Exemplary example 113 THE Gl 0.177 0.11 468 482 3.1 Example 114 B.C GA 0.436 0.11 455 459 512 23 2.5 Example 115 B.C GA 0.058 0.11 453 447 493 12 5.1 Example 116 B.CINTERRUPTED EXPERIENCE DUE TO FRACTURE OF THE STEEL SHEET DURING COLD LAMINATION Exemplary example 117 AD GA 0.026 0.13 464 474 594 16 4.6 Example 118 AD Gl 0.112 0.08 465 477 2.5 Example 119 AD GA 0.025 0.10 455 450 500 16 4.0 Example 120 AD Gl 0.056 0.00 465 474 2.2 Exemplary example
77/112
Table 8
Example Composed Type of Re-baking step -Lining step Warming-up stage First cooling step Debainite transformation process Heating rateto 600 to 750Ό Heating temperature Cooling rate at 750 to 500Ό Cooling rate from 600Ό Retention time at 300 to 470Ό Pressure ofcharge Folding radius Number of processing times experimental steel steel C / s ç C / s C / s s MPa mm times 121 AE Gl 3.2 787 3.7 7.0 74 13 450 3 122 AF Gl 3.2 771 3.5 6.9 70 17 450 3 123 AG Gl 3.4 788 3.8 6.8 68 15 450 3 124 THE GA 3.0 807 1.7 29.0 119 145 300 4 125 AHEXPERIENCEITERROMPITYFRAGAN AFRICAN LAMINATION 126 THE GA 3.4 810 2.0 23.0 70 25 300 4 127 AJEXPERIENCEITERROMPITYFRATURAN PLATE PLATE 128 AKEXPERIENCEINTERROMPITY VIVED AFRACTURE IN THE WELDING AREA IN THE DERECOZING STEP CONTINUOUS
78/112
Table 8 -continuation-
Experimental example Steel composition Steel type Annealing step - Coating step Note preheating zone deduction zone Coating zone connection oven second cooling step tempering step Cold rolling Air ratio P (H2O) 0 /P (H2) Effective amount of Al Coating bath temperature steel sheet inlet temperature Connection temperature treatment time Cooling rate Tempering temperature reduction ratio % in large scale ç ç ç s C / s Ό % 121 AE Gl 1.1 0.061 0.09 465 454 2.6 Exemplary example 122 AF Gl 1.0 0.023 0.10 457 457 2.6 Exemplary example 123 AG Gl 1.0 0.069 0.08 467 467 2.9 Exemplary example 124 THE GA 0.9 0.055 0.10 462 456 514 20 3.5 Exemplary example 125 AHINTERRUPTED EXPERIENCE DUE TO FRACTURE IN COLD LAMINATION Exemplary example 126 THE GA 1.1 0.048 0.09 462 456 507 18 2.3 Exemplary example 127 AJINTERRUPTED EXPERIENCE DUE TO FRACTURE IN THE PLATE Exemplary example 128 AKINTERRUPTED EXPERIENCE DUE TO FRACTURE IN THE WELDING AREA IN THE CONTINUOUS STEPPING STEP Exemplary example
79/112
80/112
Evaluation test [00123] In relation to the steel plate of the experimental examples produced by the above method, an evaluation test was performed as follows, and the results are shown in Tables 9 to 13 below.
Steel plate structure [00124] Initially, the structural observation of the steel layers of the experimental examples was performed using an electronic scanning microscope (SEM), structural fractions of the steel plates and average distances and average grain diameters between the grains of a retained austenite phase were measured, and are described in Tables 9 to 13 below. Here, the identification of ferrite, martensite, perlite, cementite, bainite, austenite and the balance of the structure and the observation of the existing position and the measurement of the area fraction were such that with a nital reagent and a reagent described in Japanese Laid-open Patent Publication No. 59-219473, the cross section in the rolling direction of a steel sheet or the cross section in the direction orthogonal to the rolling direction has been corrupted, and a position 1/4 of the thickness of the sheet has been observed with an enlargement 1000 to 10000 times.
[00125] Next, the number of crystal grains of the retained austenite phase was measured using an analysis of the high resolution crystal orientation by the EBSD method (Electron Back-Scatterinq Diffraction) from the results of the structural observation described above. Then the average distance between the crystal grains of the retained austenite phase was measured in the range of 10,000 pm ² or more by setting {average distance L between grains = ([observation area] / [number of crystal grains]) ¹⁷² } . In addition, the average diameter of the crystal grain of the retained austenite phase was measured by obtaining the area of each crystal grain between 30 to 300 retained austenite crystal grains chosen at random, and
81/112 obtaining the grain diameter as the equivalent circle diameter. [00126] In addition, the amount of carbon in the solid solution in the retained austenite phase was obtained by performing an x-ray diffraction test under the same conditions as the measurement described above the area fraction of the retained austenite phase in order to obtain a number of lattice shapes from the retained austenite phase, and using equation (1) described above.
[00127] Thickness of the decarburized layer in a portion of the surface layer of the steel plate and average density and average grain diameter of the oxides [00128] In relation to the thickness of a decarburized layer and a portion of the surface layer of the steel plate , the thickness cross-section in parallel to the rolling direction of each steel plate was polished mirrored and observed using m FE-SEM, the thickness of the decarburized layer of three or more positions was measured and a steel plate, and the its average value was taken as the thickness of the decarburized layer.
[00129] Furthermore, in relation to the oxides in the surface layer portion of the steel plate, initially, similarly to the above, a cross section of the thickness in parallel with the rolling direction was mirror-polished and observed using a FE- SEM, and subsequently the oxide density was measured by observing the decarburized layer for an amount of 7 pm ² and counting the number of oxides. The results are shown below in Tables 9 to 13. Furthermore, in relation to the size of the oxides, equivalent diameters of circles from 100 to 1000 grains of oxides chosen at random were averaged, and this was taken as the average grain diameter.
Appearance inspection [00130] Regarding steel sheets produced in the process
82/112 described above, an inspection of their appearances was conducted. At this time, in relation to the appearance of the steel sheet surfaces, a visual judgment was made on the status of the occurrence of non-galvanization, and the results are presented with e X in Tables 9 to 13. It is noted that X presented in Tables 9 the 13 below denotes a steel sheet in which no galvanizing of a diameter of 0.5 mm or more has been observed and which deviates from a range of appearance tolerance, and denotes other steel sheets having an appearance that is practically tolerable.
Peeling test of the coating [00131] In relation to the steel sheets produced in the above process, a peeling test of the coating was performed according to the Method of bending test for metallic materials described in JIS Z 2248 to evaluate the adhesion of the coating during the processing in which a compression pressure is applied to a steel plate. Specifically, as described in the document Hot-dip galvanized steel sheet manual, pgs. 53 - 55, after a 60 ° bend test was performed using the steel sheet, an adhesive tape was placed inside the folded portion, and that tape was removed. Then, from the peeling state of the peeling coating layer with the tape, the coating adhesion was evaluated, and the results are shown in Tables 9 to 13 below. It is noted that PRESENT presented in Tables 9 to 13 below denotes a steel plate with a peeling of 7.0 mm or more, which is practically intolerable, and denotes other steel plates having an adhesion that is practically tolerable. Here, it was used as Cellotape tape (trademark) produced by Nichiban.
Mechanical cutting property (limit of the number of times the punching) [00132] The steel sheet of each experimental example was rolled
83/112 cold, annealed and coated so that its thickness was 1.2 mm to process a steel sheet having a thickness of 1.2 mm, afterwards the punching was carried out continuously under the conditions of a die having a diameter of hole of 10.3 mmcp, an SKD11 punch material, a punch diameter of 10 mmcp (clearance 12.5%), and the burr height was measured every 50 times. At that time, the punch hole was divided into four at the 0 °, 90 °, 180 °, 270 ° positions, and the test is terminated at the point where the burr height in any direction exceeds 3.0 times the initial value, and the number of times the punch is defined as the limit number of times the punch. It is noted that in this example, to obtain various cold rolling ratios without changing the thickness of the steel sheet product, steel sheet products were produced while the thickness of the hot rolled steel sheets was varied.
Tensile property [00133] From the steel plate of each experimental example, a specimen No. 5 described in JIS Z 2201 was processed, the tensile strength (MPa) and the total elongation (%) were measured according to with the test method described in JIS Z 2241, and also the yield strength (MPa) was measured with the test method described in JIS G 0202.
[00134] In addition, in relation to the value n (hardening coefficient at work), the results of the tensile strength tests, the nominal pressure at a point where the nominal stress of 3% is 7% has been read, the pressure nominal and nominal voltage were converted into true stress and true stress, respectively, and the value n is obtained according to an equation {n = Yog (07o / ₀ / 04o / ₀ ) / log (e7o / ₀ / and ₄ o / ₀ )}. However, in relation to the steel plate having a planar elongation of less than 7%, it was obtained according to the above equation from two points, the
84/112 rated voltage point 3% and the point at which the pressure effort is maximum.
[00135] The results of the evaluation tests are presented in Tables 9 to 14 below.
Table 9
Experimental example Steel composition Steel type Structured steel plate Steel plate surface layer portion Structural fraction Austenitaretide Decarburized layer thickness Oxide density Average diameter of the oxide grain Ferrite Bainite Bainitic ferrite Martensita Spiced Martensite Retained austenite Others Amount of carbon in the solid solution Average distance between grains Average grain diameter % % % % % % % % in large scale pm pm pm oxides / m ² nm 1 THE Gl 75 3 9 5 0 8 0 0.90 2.2 0.7 1.05 1.6 E + 13 75 2 THE GA 58 2 14 16 2 7 1 0.85 3.0 0.9 0.93 2.6 E + 13 68 3 THE GA 57 2 28 5 0 7 1 0.94 4.0 1.2 1.31 2.4 E + 13 64 4 THE Gl 23 0 33 36 0 5 3 0.92 3.3 0.8 2.80 3.7 E + 13 65 5 B Gl 48 4 27 6 0 13 2 0.85 3.7 1.5 0.28 7.3 E + 12 69 6 B GA 49 0 35 4 1 11 0 0.90 2.0 0.8 0.59 1.9 E + 13 72 7 B GA 41 2 30 10 5 11 1 0.91 2.2 0.8 6.94 1.7 E + 13 92 8 B Gl 44 8 37 2 0 9 0 1.16 2.7 0.9 1.52 8.7 E + 12 82 9 Ç Gl 60 4 21 4 0 11 0 0.93 3.9 1.5 1.75 4.0 E + 13 49 10 Ç GA 49 3 30 3 0 13 2 0.95 1.5 0.6 0.95 3.0 E + 13 71 11 Ç GA 50 2 30 8 0 10 0 0.93 1.3 0.5 2.60 6.2 E + 13 42 12 Ç Gl 54 4 27 4 0 11 0 0.90 2.1 0.8 0.00 4.3 E + 11 152 13 D Gl 46 5 30 4 0 13 2 0.79 1.8 0.7 1.42 6.3 E + 12 76 14 D GA 48 3 26 5 0 17 1 0.81 3.3 1.5 1.03 9.6 E + 12 51 15 D GA 46 13 28 4 0 9 0 0.81 1.7 0.6 2.41 1.4 E + 13 81 16 D Gl 42 1 28 8 4 14 3 0.88 2.2 0.9 2.91 1.3 E + 13 75 17 AND GA 65 8 18 2 0 7 0 0.86 1.7 0.5 1.05 6.6 E + 13 58 18 AND Gl 78 0 9 4 0 9 0 0.90 3.1 1.1 3.13 8.3 E + 13 47 19 AND GA 69 8 17 2 0 4 0 0.89 0.5 0.8 2.41 5.1 E + 13 56 20 AND Gl 66 0 22 5 0 6 1 0.81 £ 9 23 2.12 2.6 E + 13 87 21 F GA 73 2 13 4 0 8 0 0.84 1.9 0.6 2.07 2.3 E + 13 50 22 F Gl 74 0 15 3 0 8 0 0.83 2.8 0.9 1.91 2.4 E + 13 96 23 F GA 81 0 14 0 0 5 0 0.89 2.0 0.5 2.05 2.1 E + 13 74 24 F Gl 66 1 22 4 0 7 0 0.81 12.9 3Z 2.21 1.7 E + 13 72 25 G Gl 4 7 23 8 0 15 0 0.84 2.4 1.1 1.29 1.9 E + 13 96 26 G Gl 44 7 28 0 8 13 0 0.80 1.4 0.6 5.11 1.8 E + 13 89 27 G GA 48 21 17 3 0 11 0 0.86 2.7 1.0 1.94 1.2 E + 13 94 28 G Gl 44 7 25 10 0 13 1 0.93 1.5 0.6 0.05 6.1 E + 11 137 29 H GA 64 11 12 8 0 5 0 0.80 2.7 0.7 3.36 9.3 E + 12 83 30 H Gl 67 5 18 3 1 5 1 0.82 4.3 1.1 1.90 8.7 E + 12 78
85/112
Table 9 -continuation-
Experimental example Steel composition Steel type Property Note Appearance inspectionLimit number of punching times Elasticity limit Tensile strength Total elongation n value coating peeling test MPa MPa % times 1 THE Gl 0 348 934 24 0.165950 Example 2 THE GA 0 654 1179 17 0.103900 Example 3 THE GA 0 611 1162 17 0.113950 Example 4 THE Gl 0 1063 1361 13 0.0591100 Exemplary example 5 B Gl 0 655 1087 20 0.123850 Example 6 B GA 0 665 1141 18 0.113900 Example 7 B GA 0 854 1239 16 0.1021150 Example 8 B Gl 0 743 1134 18 0.110400 Exemplary example 9 Ç Gl 0 645 1198 17 0.1271050 Example 10 Ç GA 0 875 1285 15 0.104950 Example 11 Ç GA 0 873 1437 13 0.087800 Example 12 Ç Gl X 754 1353 14 0.086300 Exemplary example 13 D Gl 0 774 1233 16 0.099900 Example 14 D GA 0 849 1428 13 0.097850 Example 15 D GA 0 919 1317 14 0.093950 Example 16 D Gl 0 976 1455 13 0.076950 Exemplary example 17 AND GA 0 434 958 23 0.1631050 Example 18 AND Gl 0 334 910 25 0.1961350 Example 19 AND GA 0 419 925 24 0.1631150 Example 20 AND Gl 0 485 1027 21 0.155600 Exemplary example 21 F GA 0 574 942 24 0.1771100 Example 22 F Gl 0 542 936 24 0.1701000 Example 23 F GA 0 510 911 24 0.1771050 Example 24 F Gl 0 598 952 23 0.145600 Exemplary example 25 G Gl 0 813 1164 18 0.126900 Example 26 G Gl 0 897 1151 18 0.1071100 Example 27 G GA 0 818 1166 18 0.115900 Example 28 G Gl 0 952 1332 15 0.092350 Exemplary example 29 H GA 0 510 1047 20 0.1301000 Example 30 H Gl 0 517 1067 19 0.133950 Example
86/112
Table 10
Experimental Example Steel composition Type of steel Structured steel plate Steel plate surface layer portion Structural fraction Austenitaretide Carburized bed thickness Dioxide density Diameter of the oxide grain Ferrite Bainite Ferritabainitic Martensita Martensittemperada Austenitaretide Others Amount of carbonone in solid solution Average distance between deliveries Grain diameter method % % % % % % % % in large scale pm pm pm oxides / m ² nm 31 H GA 58 4 27 7 0 4 0 0.82 4.0 0.9 2.39 8.6 E + 12 67 32 H Gl 56 6 20 0 10 6 2 0.77 4.9 1.4 1.31 4.6 E + 12 75 33 I Gl 60 9 13 8 0 9 1 0.96 1.4 0.5 2.60 4.4 E + 13 72 34 I GA 55 3 15 15 2 10 0 0.86 2.7 1.0 3.14 5.5 E + 13 64 35 I Gl 63 0 21 7 0 8 1 0.85 2.5 0.8 0.98 1.5 E + 13 56 36 I Gl 91 0 0 0 0 3 6 0.79 4.6 0.8 2.15 1.7 E + 13 61 37 J Gl 49 7 19 14 0 10 1 0.89 1.6 0.6 1.90 3.3 E + 13 51 38 J GA 55 19 20 0 0 4 2 0.94 3.7 0.9 1.95 4.9 E + 13 65 39 J GA 44 11 33 0 2 9 1 0.94 4.2 1.4 4.15 6.6 E + 13 66 40 J Gl 53 8 21 7 0 11 0 0.80 3.7 1.4 1.63 2.9 E + 13 69 41 K Gl 55 2 21 11 0 10 1 0.83 2.3 0.8 1.07 2.3 E + 13 69 42 K Gl 55 6 19 6 0 11 3 0.95 3.6 1.3 1.67 6.0 E + 13 50 43 K GA 65 6 11 10 0 8 0 0.90 3.3 1.1 2.79 3.6 E + 13 50 44 K Gl 53 4 23 11 0 9 0 0.84 £ 9 32 1.29 4.4 E + 13 66 45 L Gl 62 0 15 9 3 11 0 0.90 4.6 1.7 0.12 1.4 E + 13 42 46 L Gl 51 6 25 5 0 13 0 0.91 2.9 1.2 1.30 6.3 E + 13 43 47 L GA 57 12 19 4 0 8 0 0.90 4.1 1.3 1.36 2.8 E + 13 50 48 L GA 57 7 14 10 0 11 1 0.90 2.0 0.7 2.08 1.6 E + 14 80 49 M Gl 62 0 22 5 0 9 2 0.84 3.0 1.0 3.54 6.5 E + 13 76 50 M Gl 53 5 31 0 3 8 0 0.88 46 1.5 1.75 3.7 E + 13 47
87/112
Table 10 -continuation-
Experimental example Steel composition Steel type Property Note Appearance inspection Elasticity limit Tensile strength Total elongation alor n coating peeling test Limit number of punching times MPa MPa % times 31 H GA 0 539 1004 21 0.1441000 Example 32 H Gl 0 803 1214 16 0.113850 Example 33 I Gl 0 678 1267 15 0.1121100 Example 34 I GA 0 822 1444 12 0.0841150 Example 35 I Gl 0 618 1262 15 0.109900 Example 36 I Gl 0 350 712 23 0.1511100 Exemplary example 37 J Gl 0 868 1406 13 0.0821050 Example 38 J GA 0 570 1006 21 0.1421100 Example 39 J GA 0 806 1231 16 0.0891300 Example 40 J Gl X 711 1227 16 0.107950 Exemplary example 41 K Gl 0 686 1271 15 0.094900 Example 42 K Gl 0 779 1359 14 0.0911100 Example 43 K GA 0 673 1335 14 0.0991150 Example 44 K Gl 0 734 1274 15 0.095350 Exemplary example 45 L Gl 0 735 1415 13 0.087800 Example 46 L Gl 0 894 1384 14 0.0891050 Example 47 L GA 0 669 1207 17 0.1061000 Example 48 L GA 0 720 1389 13 0.081 gift 1150 Exemplary example 49 M Gl 0 545 1065 20 0.1231200 Example 50 M Gl 0 707 1214 16 0.1021050 Example
88/112
Table 10 -continuation-
Exampleex- Composition Type Structured steel plate Steel plate surface layer portion Structural fraction Austenitaretide Carburized bed thickness Dioxide density Diameter of the oxide grain Ferrite Balnlta Ferritabainitic Martensita Martensittemperada Austenitaretide Others Amount of carbonone in solid solution Average distance between deliveries Grain diameter method perimental steel steel % % % % % % % % in large scale pm pm pm oxides / m ² nm 51 M GA 54 20 14 6 0 6 0 0.91 3.9 1.1 0.68 2.2 E + 13 66 52 M Gl 58 26 16 0 0 0 0 0.81 1.31 3.0 E + 13 41 53 N Gl 70 0 16 7 0 7 0 0.82 2.7 0.8 2.07 1.0 E + 13 71 54 N Gl 76 2 9 6 0 7 0 0.84 3Z U. 3.47 1.5 E + 13 66 55 N GA 67 4 20 3 0 5 1 0.84 1.8 0.5 1.40 1.2 E + 13 89 56 N GA 65 3 19 7 0 6 0 0.93 2.1 0.6 1.80 1.8 E + 13 70 57 0 Gl 61 8 20 4 0 7 0 0.75 2.4 0.7 1.57 3.8 E + 12 87 58 0 GA 60 23 5 2 0 6 4 0.81 4.0 1.1 2.00 7.2 E + 12 TL 59 0 GA 49 14 18 13 0 5 1 0.77 4.8 1.2 1.51 6.4 E + 12 85 60 0 Gl 47 18 23 1 0 1 10 0.73 82 0.7 3.70 5.8 E + 12 98
89/112
Table 10 -continuation-
Experimental example51 Steel compositionM GA steel type Property Note Appearance inspection 0 Elasticity limit Tensile strength Total elongation Value n coating peeling test Limit number of punching times MPa MPa % times 669 1162 17 0.106900 Example 52 M Gl 0 427 842 16 0.116> 2000 Exemplary example 53 N Gl 0 482 1114 18 0.133950 Example 54 N Gl 0 343 994 22 0.1781100 Example 55 N GA 0 468 928 24 0.170950 Example 56 N GA X 520 1140 18 0.126950 Exemplary example 57 0 Gl 0 551 1076 19 0.123900 Example 58 0 GA 0 506 1002 21 0.137950 Example 59 0 GA 0 698 1145 17 0.098850 Example 60 0 Gl 0 533 885 17 0.0891000 Exemplary example
90/112
Table 11
Experimental example Steel composition Steel type Structured steel plate Steel surface layer portion Structural fraction Austenitaetida Decarburized layer thickness Oxide density Diameter of the oxide grain Ferrite Bainite Bainitic ferrite Martensita Spiced Martensite Retained austenite Others Amount of carbon in the solid solution Average distance between grains Average grain diameter % % % % % % % % in large scale pm pm pm oxides / m ² 1.3 E + 13 nm 61 P GA 63 15 10 7 0 4 1 0.79 3.3 0.8 0.50 70 62 P Gl 58 6 24 2 3 7 0 0.86 1.9 0.6 1.67 3.8 E + 13 76 63 P GA 62 8 13 8 0 8 3 0.89 2.9 0.8 2.21 1.8 E + 13 78 64 P Gl 48 9 23 12 0 8 0 0.86 to aã 2.40 2.0 E + 13 86 65 Q GA 45 33 0 12 0 8 2 0.93 2.5 0.8 0.46 1.1 E + 13 62 66 Q GA 53 2 31 1 0 12 1 0.98 3.8 1.5 1.81 1.1 E + 13 80 67 Q GA 40 12 33 0 3 12 0 0.89 3.5 1.4 1.40 1.3 E + 13 75 68 Q Gl 45 9 23 8 0 14 1 0.77 2.1 0.9 19.0 5.1 E + 13 87 69 R Gl 54 2 23 8 0 13 0 0.92 1.7 0.7 1.63 1.9 E + 14 45 70 R GA 56 6 17 5 0 15 1 0.92 2.4 1.0 3.19 4.9 E + 14 37 71 R GA 44 7 35 2 0 12 0 0.99 4.4 1.7 2.40 6.0 E + 14 39 72 R GA 51 18 14 0 0 1 16 0.64 there 1.1 2.31 1.4 E + 14 33 73 s GA 51 4 27 5 0 12 1 0.83 3.5 1.4 3.36 3.2 E + 13 60 74 s Gl 52 6 30 3 0 9 0 0.79 4.7 1.6 2.28 2.2 E + 13 86 75 s GA 56 0 19 0 13 11 1 0.81 2.5 0.9 2.81 1.4 E + 13 68 76 s Gl 44 8 23 9 0 14 2 0.81 to 3.3 2.17 2.6 E + 13 62 77 T Gl 50 0 29 7 0 12 2 0.93 2.0 0.8 2.19 1.9 E + 13 77 78 T Gl 46 6 27 7 0 13 1 0.87 3.8 1.6 1.83 2.1 E + 13 84
91/112
Table 11 -continuation-
Experimental example Steel composition Steel type Property Note Appearance inspectionLimit number of punching times Elasticity limit Tensile strength Total elongation n value coating peeling test MPa MPa % times 61 P GA 0 565 1110 18 0.116850 Example 62 P Gl 0 657 1146 18 0.1231000 Example 63 P GA 0 514 993 22 0.1411000 Example 64 P Gl 0 747 1226 16 0.097250 Exemplary example 65 Q GA 0 866 1384 13 0.081950 Example 66 Q GA 0 624 1115 19 0.126900 Example 67 Q GA 0 820 1214 17 0.104900 Example 68 Q Gl 0 672 1151 18 0.1211200 Exemplary example 69 R Gl 0 733 1282 15 0.0971300 Example 70 R GA 0 724 1301 15 0.099900 Example 71 R GA 0 826 1312 15 0.0901200 Example 72 R GA X 531 860 26 0.161 GIFT 1450 Exemplary example 73 s GA 0 846 1292 15 0.0981150 Example 74 s Gl 0 850 1319 14 0.083950 Example 75 s GA 0 1089 1409 13 0.0941000 Example 76 s Gl 0 957 1408 13 0.091500 Exemplary example 77 T Gl 0 717 1248 16 0.1071000 Example 78 T Gl 0 926 1420 13 0.088900 Example
92/112
Table 11 -continuation-
Experimental example Steel composition Steel type Structured steel plate Steel surface layer portion Structural fraction Austenitaetida Decarburized layer thickness Oxide density Diameter of the oxide grain Ferrite Bainite Bainitic ferrite Martensita Spiced Martensite Retained austenite Others Amount of carbon in the solid solution Average distance between grains Average grain diameter % % % % % % % % in large scale pm pm pm oxides / m ² nm 79 T GA 53 8 19 5 0 14 1 0.98 2.4 1, the 3.43 3.0 E + 13 1 80 T Gl 45 8 24 11 0 12 0 0.84 6.9 n 2.18 3.1 E + 13 100 81 u Gl 59 12 13 8 0 8 0 0.81 1.9 0.6 0.14 3.1 E + 12 53 82 u Gl 59 9 11 12 0 z 2 0.79 4.6 1.3 1.27 5.4 E + 12 85 83 u GA 50 13 25 6 0 6 0 0.96 2.5 0.7 2.65 1.5 E + 13 89 84 u Gl 50 4 22 14 2 8 0 0.88 3J5 1.1 11.5 2.9 E + 13 83 85 V Gl 50 10 20 6 0 14 0 0.90 3.3 1.4 2.64 1.6 E + 15 75 86 V Gl 48 3 18 0 21 10 0 0.89 2.0 0.7 2.62 1.5 E + 14 55 87 V GA 50 0 23 14 0 12 1 0.88 4.0 1.5 1.98 1.1 E + 14 58 88 V Gl 55 5 17 8 0 15 0 0.97 £ 5 2J5 2.48 4.1 E + 13 73 89 w Gl 83 0 7 3 0 7 0 0.93 3.1 0.9 2.61 9.7 E + 13 63 90 w GA 67 0 16 11 0 5 1 0.89 4J. 1.0 2.29 4.4 E + 13 54
93/112
Table 11 -continuation-
Experimental example Steel composition Steel type Property Note Appearance inspectionLimit number of punching times Elasticity limit Tensile strength Total elongation n value coating peeling test MPa MPa % times 79 T GA 0 787 1305 15 0.1081100 Example 80 T Gl 0 880 1390 13 0.083350 Exemplary example 81 u Gl 0 650 1091 19 0.130850 Example 82 u Gl 0 760 1292 14 0.082850 Example 83 u GA 0 774 1163 17 0.1111000 Example 84 u Gl X 790 1192 17 0.107400 Exemplary example 85 V Gl 0 739 1263 16 0.1051250 Example 86 V Gl 0 978 1215 16 0.1091350 Example 87 V GA 0 775 1366 14 0.0831150 Example 88 V Gl 0 702 1270 16 0.102550 Exemplary example 89 w Gl 0 278 92 24 0.1861250 Example 90 w GA 0 516 1081 19 0.1321150 Example
94/112
Table 12
Experimental example Steel composition Steel type Structured steel plate Steel surface layer portion Structural fraction Retained austenite Decarburized layer thickness Oxide density Average diameter of the oxide grain Ferrite Bainite Bainitic ferrite Martensita Martensittemperada AusteniteRetained Others Amount of carbon in the solid solution Average distance between grains Average grain diameter % % % % % % % % in large scale □ m □ m □ m oxides / m ² 9.5 E + 13 nm 91 W GA 62 6 24 0 0 8 0 0.95 3.9 1.3 3.48 61 92 W GA 64 11 19 0 0 6 0 1.09 1.4 0.4 1.80 3.5 E + 13 65 93 X Gl 49 10 21 7 0 11 2 0.78 3.2 1.2 2.87 8.0 E + 13 45 94 X Gl 54 10 23 0 0 13 0 0.94 16 0.7 5.08 5.2 E + 13 61 95 X GA 54 13 15 6 2 10 0 0.86 3.5 1.2 2.05 3.6 E + 13 51 96 X Gl 50 3 14 25 7 1 0 0.61 8.0 0.7 1.88 1.3 E + 14 72 97 Y Gl 57 7 25 4 0 7 0 0.90 4.5 1.0 2.97 2.0 E + 13 84 98 Y Gl 62 0 16 12 2 8 0 0.81 3.3 1.1 1.30 1.9 E + 13 44 99 Y GA 66 5 13 7 0 9 0 0.81 2.3 0.8 2.40 2.6 E + 13 57 100 Y Gl 69 3 10 8 0 8 2 0.92 £ 9 Zã 1.83 3.1 E + 13 73 101 z Gl 58 3 18 7 0 12 2 0.88 2.9 1.1 1.10 2.2 E + 13 80 102 z Gl 46 8 28 4 0 14 0 0.93 21 1.1 0.53 4.2 E + 13 51 103 z GA 49 9 23 2 0 16 1 0.92 1.2 0.6 0.06 1.8 E + 13 69 104 z Gl 53 5 23 6 0 12 1 0.91 6J5 2J5 1.81 5.4 E + 13 40 105 AA Gl 66 0 25 2 0 6 1 0.88 2.6 0.7 3.05 4.9 E + 13 70 106 AA Gl 56 13 18 8 0 4 1 0.81 3.9 0.9 2.07 2.2 E + 13 72 107 AA GA 62 4 16 11 0 7 0 0.82 4.9 1.4 1.38 3.1 E + 13 88
95/112
Table 12 -continuation-
Example Composed Type of Structured steel plate Steel surface layer portion Structural fraction Austenite retained Decarburized layer thickness Oxide density Average diameter of the oxide grain Ferrite Bainite Bainitic ferrite Martensita Martensittemperada AusteniteRetained Others Amount of carbon in the solid solution Average distance between grains Average grain diameter experimental steel steel % % % % % % % % in large scale pm pm pm oxides / m ² nm 108 AA Gl 64 15 14 1 0 0 6 0.91 3.8 0.8 2.24 3.5 E + 13 66 109 AB Gl 58 18 7 5 0 12 0 0.94 2.0 0.8 1.54 7.4 E + 13 53 110 AB Gl 55 3 25 3 0 14 0 0.90 2.4 1.0 2.82 8.6 E + 13 55 111 AB GA 64 0 13 13 0 9 1 0.85 3.1 1.0 0.81 9.8 E + 13 57 112 AB Gl 50 11 17 8 0 13 1 0.93 11.8 49 1.43 8.0 E + 13 39 113 B.C Gl 68 5 14 3 0 10 0 0.88 1.6 0.6 2.87 3.0 E + 13 83 114 B.C GA 49 12 23 1 2 12 1 0.92 3.3 1.3 8.23 6.7 E + 13 89 115 B.C GA 53 7 25 5 0 9 1 0.84 1.3 0.4 1.58 1.6 E + 13 71 116 B.C EXPERIENCEINTERROMPITYVICE AFRACTURE OF HOT AAMONIC LAMINATION 117 AD GA 47 6 15 19 3 8 2 0.86 1.7 0.5 1.34 7.1 E + 13 38 118 AD Gl 66 0 12 10 0 10 2 0.93 22 0.8 2.83 8.1 E + 13 63 119 AD GA 63 2 21 6 0 8 0 0.90 3.3 1.1 1.87 7.3 E + 13 55 120 AD Gl 59 9 13 11 0 9 0 0.82 2J3 1.0 1.41 1.1 E + 14 55
96/112
Table 12 -continuation-
Experimental example Steel composition Steel type Property Note Appearance inspectionLimit number of times of operation Elasticity limit Tensile strength Total elongation n value coating peeling test MPa MPa % times 91 W GA 0 511 987 22 0.1511300 Example 92 W GA 0 432 908 25 0.171350 Exemplary example 93 X Gl 0 878 1256 16 0.0951300 Example 94 X Gl 0 820 1240 16 0.1121350 Example 95 X GA 0 975 1407 13 0.0921050 Example 96 X Gl 0 1087 1459 11 0.060900 Exemplary example 97 Y Gl 0 614 1093 19 0.1221000 Example 98 Y Gl 0 638 1192 17 0.1111000 Example 99 Y GA 0 515 1096 19 0.1251100 Example 100 Y Gl 0 469 1082 19 0.140500 Exemplary example 101 z Gl 0 590 1139 18 0.130900 Example 102 z Gl 0 1009 1453 13 0.082850 Example 103 z GA 0 762 1242 17 0.112850 Example 104 z Gl 0 707 1194 17 0.114450 Exemplary example 105 AA Gl 0 520 1098 19 0.1321150 Example 106 AA Gl 0 642 1191 16 0.0951000 Example 107 AA GA 0 571 1131 18 0.132950 Example
97/112
Table 12 -continuation-
Experimental example Steel composition Steel type Property Note Appearance inspectionLimit number of times of operation Elasticity limit Tensile strength Total elongation n value coating peeling test MPa MPa % times 108 AA Gl 0 443 844 16 0.0761100 Exemplary example 109 AB Gl 0 693 1394 13 0.0971100 Example 110 AB Gl 0 699 1271 16 0.1161250 Example 111 AB GA 0 649 1368 13 0.098950 Example 112 AB Gl 0 773 1319 15 0.103350 Exemplary example 113 B.C Gl 0 498 1033 21 0.1371100 Example 114 B.C GA 0 798 1276 15 0.093900 Example 115 B.C GA 0 764 1279 15 0.088950 Example 116 B.C EXPERIENCEINTERROMPITYVICE AFRACTURE OF HOT AAMONIC LAMINATION Exemplary example 117 AD GA 0 807 1296 15 0.098950 Example 118 AD Gl 0 550 1212 17 0.1201100 Example 119 AD GA 0 611 1124 18 0.1201000 Example 120 AD Gl 0 665 1269 15 0.095 GIFT 1100 Exemplary example
98/112
Table 13
Experimental example Steel composition Type of steel Structured steel plate Structural fraction Austenitaretide Ferrite Bainite Bainitic ferrite Martensita Spiced Martensite Retained austenite Others Amount of carbon in the solid solution Average distance between grains Average grain diameter % % % % % % % % in large scale pm pm 121 AE Gl 88 0 5 3 0 4 0 0.82 4.4 1, the 122 AF Gl 31 3 33 7 0 26 0 0.84 1.4 0.8 123 AG Gl 87 0 3 1 0 9 0 0.86 0.9 0.3 124 THE GA EXPERIENCEINTERROMPITYVIVID ADESVATION OF THE ASSESSED SHEET 125 AHEXPERIENCEINTERROMPITYVICE AFRACTURE NALAMINATION AFRIO 126 Al GA 61 11 15 5 0 6 2 0.84 1.9 0.8 127 AJEXPERIENCEINTERROMPITYFRATHERAN PLATE 128 AKEXPERIENCEINTERROMPETIVITYFRACTURE IN THE DESOLDINGZONE IN THE DERECOZING STEP CONTINUOUS
99/112
Table 13- continued-
Experimental example Steel composition Steel type Portion of the surface layer of the steel sheet Property Note Decarburized Layer Thickness Oxide density Average diameter of the oxide grain Appearance inspection Limit number of punching times Elasticity limit Tensile strength Total elongation n value coating peeling test pm oxides / m ² nm MPa MPa % times 121 AE Gl 1.54 1.7 E + 13 67 0 371 755 31 0.2391000 Comparative example 122 AF Gl 1.07 5.2 E + 13 63 0 1327 1814 11 0.073950 Comparative example 123 AG Gl 1.70 8.9 E + 12 74 0 460 829 29 0.2341050 Comparative example 124 THE GA INTERRUPTED EXPERIENCE DUE TO DEVIATION OF PLATE THICKNESS Comparative example 125 AHINTERRUPTED EXPERIENCE DUE TO FRACTURE IN COLD LAMINATION Comparative example 126 Al GA 2.58 1.2E + 11 212 0 421 930 21 0.153 400 Comparative example 127 AJINTERRUPTED EXPERIENCE DUE TO FRACTURE ON THE PLATE Comparative example 128 AKINTERRUPTED EXPERIENCE DUE TO FRACTURE IN THE WELDING AREA IN THE CONTINUOUS STEPPING STEP Comparative example
100/112
101/112
Results of the evaluation [00136] As shown in Tables 9 to 13 in the high-strength hot-dip galvanized steel sheets and the high-strength hot-dip galvanized steel sheets of the examples having the steel compositions defined herein invention and produced by the production conditions defined in the present invention (examples of the present invention: see the Notes columns in Tables 1 to 13), the volume fraction of the ferrite phase and the austenite phase retained in the steel plate structure, the amount of carbon in the solid solution, the average grain diameter, and the average distance between grains in the retained austenite phase, and the thickness of the decarburized layer, the average grain diameter, and the average density of the oxides in the surface layer portion of the plate steel, as well as the hardening coefficient at work (value n) were all in the ranges defined in claim 1 of the present invention. Then, the steel sheets of the present invention were excellent in appearance property of the coating layer and in peeling property and excellent in tensile properties of the yield strength, tensile strength, total elongation and value n, and also the number of punching times is 650 times or more, which proves that they are excellent in mechanical cutting properties. Therefore, from these evaluation results, it was found that the examples of the high-strength hot-dip galvanized steel sheet and the high-strength hot-dip galvanized steel sheet of the present invention have excellent ductility and mechanical cutting property simultaneously while ensuring maximum tensile strength of 900 MPa or more.
[00137] On the other hand, the hot-dip galvanized steel sheet and the hot-dip galvanized steel sheet linked from the comparative examples do not satisfy the steel composition and the
102/112 production conditions defined in the present invention, and do not satisfy one or more of the steel properties defined in the present invention. Thus, the comparative examples, as will be described below, result in that any item of the tensile properties or one among the items of appearance of the steel layer and peeling property of the coating do not satisfy the desired properties. [00138] In hot-dip galvanized steel sheet of experimental example 4, the average cooling rate of 750 to 650Ό in the annealing step exceeds the defined range of the present invention, and the volume fraction of the ferrite phase in the sheet structure steel and less than the defined range of the present invention. Thus, it resulted in a low n value of 0.059, which proves that it has lower ductility. [00139] In the hot dip galvanized steel sheet of experimental example 8, the retention time between 300 to 470Ό in the annealing step greatly exceeded the defined range of the present invention, and the amount of carbon in the solid solution in the retained austenite phase greatly exceeds the defined range of the present invention. Thus, it resulted in a low limit of punching times, 400 times, which proves that it has a lower mechanical cutting property.
[00140] The hot dip galvanized steel sheet of experimental example 12 is produced in an atmosphere where the ratio of the partial pressure {P (H ₂ O) / P (H ₂ )} between water vapor and hydrogen in the The reduction zone in the annealing step is zero and the water vapor is barely contained, and the decarburized layer is not generated in the surface layer portion of the steel plate. In addition, since the average grain diameter of the oxides is large, the density of the oxides is low. The thickness of the decarburized layer, the average diameter and grain of the oxides, and the density of the oxides all deviate from the defined ranges of the present invention, and resulted in a number
103/112 ro significantly low punching times limit, 300 times, which proves that it has lower mechanical cutting properties. [00141] In the hot dip galvanized steel sheet of experimental example 16, the maximum heating temperature of the plate in the hot rolling step is less than the defined range of the present invention. This results in an n value of 0.076 that is less than the defined range of the present invention, which proves that it has less ductility.
[00142] In the hot-dip galvanized steel sheet of experimental example 20, the average cooling rate in the annealing step is less than the defined ranges of the present invention, and the average grain diameter and the average distance between grains in the phase retained austenite exceeds the defined ranges of the present invention. Thus, it resulted in a low limit on the number of punching times, 600 times, which proves that it has lower mechanical cutting properties.
[00143] In the hot dip galvanized steel sheet of experimental example 24, the average heating rate at 600 to 750Ό in the annealing step greatly exceeds the defined range of the present invention, and the average grain diameter and the average distance between grains of the retained austenite phase exceeded the defined ranges of the present invention. Thus, it resulted in a low puncture limit number, 600 times, which proves that it has lower mechanical cutting properties.
[00144] In the hot dip galvanized steel sheet of experimental example 28, the amount of air is small because the air ratio of the preheating zone in the annealing step is 0.4 which is less than the defined range of the present invention , and thus the generation of oxides in the surface layer portion of the steel sheet is not adequate. That is, the average grain diameter of the oxides is large,
104/112 and thus the density of the oxides is low, which deviates both from the defined range of the present invention. Thus, it resulted in a significantly low number of times of the punch, 350 times, which proves that it has inferior mechanical cutting property.
[00145] In the hot-dip galvanized steel sheet of experimental example 36, the maximum heating temperature in the annealing step is less than the defined range of the present invention, and thus the volume fraction of the ferrite phase in the sheet structure. steel was 91%, which exceeds the defined range of the present invention. Meanwhile, the volume fraction of other structures is very small. Thus, it resulted in a very low elasticity limit and tensile strength between the tensile properties, which proves that it has a lower strength property.
[00146] In the hot dip galvanized steel sheet of experimental example 40, the effective amount of Al in the coating bath in the coating step exceeds the defined range of the present invention, and thus there are many positions in which peeling has occurred, resulting in in X in the appearance test.
[00147] In the hot-dip galvanized steel sheet connected to experimental example 44, the cooling stop temperature in the hot rolling step is less than the defined range of the present invention, and both the average grain diameter and the distance average between grains of the retained austenite phase exceeded the defined ranges of the present invention. Thus, it resulted in a significantly low limit number of times of the punch, 350 times, which proves that it has inferior mechanical cutting property.
[00148] The hot dip galvanized steel sheet of experimental example 48 is an example in which the treatment time, when the bonding treatment is carried out on the coating layer after the coating step, is very long, and so the go down
105/112 coating coating occurred in the coating peeling test.
[00149] In the hot dip galvanized steel sheet of experimental example 52, the average cooling rate at 750 to 650Ό in the annealing step is less than the range defined in the present invention, the volume fraction in the bainite phase and in the bainitic ferrite in the steel plate structure are large, and in the meantime the martensite phase, the tempered martensite phase, the retained austenite phase, and other phases are not generated. Thus, it resulted in a low elasticity limit and tensile strength, which proves that it has lower strength properties.
[00150] The hot dip galvanized steel sheet of experimental example 56 is an example in which the treatment time when the bonding treatment is carried out on the coating layer after the coating step is very short, and thus peeling has occurred in many positions, resulting in X in the appearance test.
[00151] In the hot dip galvanized steel sheet of experimental example 60, the average cooling rate after the cooling step is less than the defined range of the present invention, and thus the volume fraction of the austenite phase retained in the structure of the steel plate and smaller than the defined range of the present invention. Meanwhile, the volume fraction of the other structures is high. In addition, the average distance between grains of the retained austenite phase exceeds the defined range of the present invention. Thus, it resulted in a low elasticity limit, tensile strength, and total elongation, which proves that it has a lower cut property.
[00152] In the hot-dip galvanized steel sheet of experimental example 64, the temperature of finishing the rolling in the hot rolling stage exceeds the defined range of this
106/112 convention, and thus both the average grain diameter and the average distance between grains of the retained austenite phase exceed the defined ranges of the present invention. Thus, it resulted in a significantly low limit of punching times, 250 times, which proves that it has lower mechanical cutting properties.
[00153] In the hot-dip galvanized steel sheet of experimental example 68, the partial pressure ratio {P (H ₂ O) / P (H ₂ )} between water vapor and hydrogen in the reduction zone in the annealing deviates from the defined range of the present invention, and the thickness of the decarburized layer on the surface portion of the steel sheet exceeds the defined range of the present invention. Thus, steel sheet of experimental example 68 has very low fatigue strength, becoming a sheet that does not stand up to practical use.
[00154] In the hot dip galvanized steel plate bonded from experimental example 72, the treatment time when the bonding time is carried out in the coating layer, after the coating step exceeds the defined range of the present invention. Thus, the volume fraction of the austenite phase retained in the steel sheet structure is less than the defined range of the present invention, and meanwhile the volume fraction of the other structures is high. In addition, the amount of carbon in the solid solution in the retained austenite phase is less than the defined range of the present invention, and the average distance between grains exceeds the defined range of the present invention. Thus, X resulted in the appearance test, and the peeling of the coating occurred in the peeling test of the coating. In addition, it resulted in a low elasticity limit and tensile strength, which proves that it is inferior in strength, ductility and mechanical cutting property.
[00155] In the hot-dip galvanized steel sheet of experimental example 76, the bending in the annealing step does not
107/112 was performed, and thus the average grain diameter and the average distance between grains of the retained austenite phase exceeded the defined ranges of the present invention. Thus, it resulted in a low limit of punching times, 500 times, which proves that it has lower mechanical cutting properties.
[00156] In the hot dip galvanized steel sheet of experimental example 80, the temperature of the cooling stop in the hot rolling step exceeds the defined range of the present invention, and then the average grain diameter and the average distance between grains of the retained austenite phase exceed the defined ranges of the present invention. Thus, it resulted in a significantly low limit number of times of the punch, 350 times, which proves that it has inferior mechanical cutting property.
[00157] In the hot-dip galvanized steel sheet of experimental example 84, the amount of air is very large because the air ratio of the preheating zone in the annealing step exceeds the defined range of the present invention, and thus the thickness of the decarburized layer in the surface layer portion of the steel sheet in the surface layer portion of the steel sheet exceeds the defined range of the present invention. Thus, it is inferior in coating properties, the result of the appearance test is then an X evaluation and, in addition, it resulted in a low limit number of times of punching, 400 times, which proves that it has inferior property of mechanical cutting.
[00158] In the hot dip galvanized steel sheet of experimental example 88, the bending radius of the bend in the annealing step exceeds the defined range of the present invention, and then the average grain diameter and the average distance between grains in the phase retained austenite exceeds the defined ranges of the present invention. Thus, it resulted in a low limit of puncture times
108/112 to, 550 times, which proves that it has inferior mechanical cutting property.
[00159] In hot-dip galvanized steel plate bonded from experimental example 92, the retention time at 300 to 470Ό in the annealing step greatly exceeds the defined range of the present invention, and the amount of carbon in the solid solution in the austenite phase retained value greatly exceeds the defined range of the present invention. Thus, it resulted in a significantly low limit number of times of punching, 350 times, which proves that it has inferior mechanical cutting property.
[00160] In the hot dip galvanized steel sheet of experimental example 96, the retention time at 300 to 470Ό in the annealing step is less than the defined range of the present invention, the volume fraction of the retained austenite phase is less than the defined range of the present invention, and meanwhile the volume fraction of the martensite phase is high. Thus, the amount of carbon in the solid solution in the retained austenite phase is less than the defined range of the present invention, and the average distance between grains exceeds the defined range of the present invention. Thus, it resulted in a low n value of 0.060, which proves that it has a lower mechanical cutting property.
[00161] In the hot-dip galvanized steel sheet of experimental example 100, the tension in the temperature range of 300 to 470Ό was not applied in the annealing step, and therefore the average grain diameter as far as the average distance between grains of the retained austenite phase exceeds the defined ranges of the present invention. Thus, it resulted in a low limit on the number of times the punching, 500 times, which proves that it has inferior mechanical cutting properties. Thus, it resulted in a low limit number of times of punching, 500 times, which proves that it has inferior mechanical cutting property.
109/112 [00162] In the hot dip galvanized steel sheet of experimental example 104, the reduction ratio in the cold rolling step is less than the defined range of the present invention, and therefore both the average grain diameter and the average distance between grains of the austenite phase retained the defined ranges of the present invention. Thus, it resulted in a low limit value of the number of times of the punch, 450 times, which proves that it has inferior mechanical cutting property.
[00163] In the hot dip galvanized steel sheet of experimental example 108, the average cooling rate from 650Ό in the annealing step is less than the defined range of the present invention. It turned out that the retained austenite phase is barely generated, and in the meantime many other structures are generated. Thus, the tensile strength is low and the value n is less than the defined range of the present invention, which proves that it has lower strength and ductility.
[00164] In hot dip galvanized steel sheet of experimental example 112, the slow cooling time up to 400Ό in the hot rolling step is less than the defined range of the present invention, and both the average grain diameter and the distance average between grains of the retained austenite phase exceeds the defined ranges of the present invention. Thus, it resulted in a significantly low number of punch times, 350 times, which proves that it has inferior mechanical cutting properties.
[00165] In experimental example 116, the steel sheet fractured because the reduction ratio in the cold rolling step is very large, and the hot dip galvanized steel sheet cannot be produced.
[00166] On hot-dip galvanized steel sheet of experimental example 120, the peeling of the coating layer
110/112 occurred in the coating peeling test due to the fact that the effective amount of Al in the coating bath in the coating step is 0%.
[00167] The hot-dip galvanized steel sheets of experimental examples 121 to 123 are examples in which chemical compositions deviated from predetermined ranges. Among others, in the experimental example 121, the C content is less than the lower limit defined in the present invention, and so it turned out that the ferrite phase is largely generated in the steel plate structure and the tensile strength is low, which proves that it has lower strength property. In addition, in experimental example 122, the amount of C exceeds the upper limit defined in the present invention, and so it resulted that a large amount of retained austenite phase is generated in the steel sheet structure, and the n value is low, which proves that she has inferior ductility. In addition, in experimental example 123, the amount of Mn is less than the lower limit defined in the present invention, and so it resulted that a large amount of ferrite phase is generated in the structure of the steel layer, and the tensile strength is low, the which proves that it has inferior resistance property.
[00168] The hot dip galvanized steel sheet of experimental example 124 is an example in which the voltage b [in the temperature range 300 to 470Ό exceeded the defined range a of the present invention in the annealing step. Here is an example in which the thickness of the steel sheet after the annealing step has decreased compared to the thickness of the steel sheet before the annealing step, the precision of the predetermined layer thickness cannot be obtained, and experiment has been interrupted .
[00169] In experimental example 125, the Si content is large, the steel sheet fractured in the cold rolling stage, and the experiment was interrupted.
111/112 [00170] In the hot-dip galvanized steel sheet of experimental example 126, the Si content is small, the generation of oxides in the surface layer portion of the steel sheet is not adequate, and the density oxides deviate from the range defined in the present invention. Thus, it resulted in a low limit number of times of the punch, 400 times, which proves that it has inferior mechanical cutting property.
[00171] In the experimental example 127, the Mn content is large, the lacquer fractured until it was subjected to the hot lamination stage after the end of the casting, and the experiment was interrupted.
[00172] In experimental example 128, the Al content is large, the portion welded to the front and rear fractured during the annealing step, and the experiment was interrupted.
[00173] From the results of the examples as described, it is clear that the high-strength hot-dip galvanized steel sheet and the high-strength hot-dip galvanized steel sheet excellent in mechanical cutting properties of the present invention have excellent ductility, do not deteriorate production equipment or the like, and have high mechanical cutting properties, while guaranteeing high strength with maximum tensile strength of 900 MPa or more.
INDUSTRIAL APPLICABILITY [00174] According to the present invention, for example, in applications such as elements obtained by forming a pressed steel sheet or the like, excellent ductility and mechanical cutting properties are obtained and excellent strength and working capacity, while ensuring high strength with maximum tensile strength of 900 MPa or more. Thus, applying the present invention, for example, to the field of automotive or similar elements in particular, merits such
112/112 such as the improvement in safety accompanied by an increase in the strength of the vehicle chassis, improvement in the work capacity for processing an element, and the like, can be used sufficiently, and their social contributions are immeasurable.

权利要求:
Claims (5)
[1]
claims
1. High-strength hot-dip galvanized steel sheet with a thickness of 0.6 to 5.0 mm, characterized by the fact that it comprises a coating layer on a surface of the steel sheet consisting, in% by mass, in:
C: 0.075 to 0.400%,
Si: 0.01 to 2.00%,
Mn: 0.80 to 3.50%,
P: 0.0001 to 0.100%,
S: 0.0001 to 0.0100%,
Al: 0.001 to 2.00%,
N: 0.0001 to 0.0100%,
O: 0.0001 to 0.0100% and optionally, also consisting of, in% mass, one or more elements among
Ti: 0.001 to 0.150%,
Nb: 0.001 to 0.100%,
V: 0.001 to 0.300%,
Cr: 0.01 to 2.00%,
Ni: 0.01 to 2.00%,
Cu: 0.01 to 2.00%,
Mo: 0.01 to 2.00%,
B: 0.0001 to 0.0100%,
W: 0.01 to 2.00%, and
0.0001 to 0.0100% in the total of one or more elements between Ca, Ce, Mg, Zr, La, and REM, with the balance being made up of iron and the inevitable impurities, where:
in a range of 1/8 of the thickness to 3/8 of the thickness with 1/4 of the thickness of the plate being the center from the surface of the
Petition 870190015128, of 02/14/2019, p. 4/12
[2]
2/5 steel plate, the steel plate structure contains at least 40 to 90% of a ferrite phase and 3% or more of an austenite phase retained in fraction of volume;
in the retained austenite phase, the amount of solid carbon solution in the phase is 0.70 to 1.00%, the average grain diameter is 2.0 pm or less, and the average distance between grains is 0.1 to 5 , 0 pm;
the thickness of a decarburized layer in a portion of the steel plate surface layer is 0.01 to 10.0 pm, the average grain diameter of the oxides contained in the steel plate surface layer is 30 to 120 nm and the its average density is 1.0 χ 10 ¹² oxides / m ² or more; and in addition, the hardening coefficient at work (n value) during a plastic deformation of 3 to 7% is 0.080 or more on average.
2. High strength bonded hot dip galvanized steel sheet, characterized by the fact that it is formed by the coating layer bonding of the high strength hot dip galvanized steel sheet, as defined in claim 1.
[3]
3. Production method of a high-strength hot-dip galvanized steel sheet, characterized by the fact that it consists of:
a hot lamination step of heating to 1180 ° C or more a plate having chemical components consisting, in% by mass, of:
C: 0.075 to 0.400%,
Si: 0.01 to 2.00%,
Mn: 0.80 to 3.50%,
P: 0.0001 to 0.100%,
S: 0.0001 to 0.0100%,
Al: 0.001 to 2.00%,
Petition 870190015128, of 02/14/2019, p. 5/12
3/5
N: 0.0001 to 0.0100%,
O: 0.0001 to 0.0100% and optionally, also consisting of, in% mass, one or more elements among
Ti: 0.001 to 0.150%,
Nb: 0.001 to 0.100%,
V: 0.001 to 0.300%,
Cr: 0.01 to 2.00%,
Ni: 0.01 to 2.00%,
Cu: 0.01 to 2.00%,
Mo: 0.01 to 2.00%,
B: 0.0001 to 0.0100%,
W: 0.01 to 2.00%, and
0.0001 to 0.0100% in the total of one or more elements between Ca, Ce, Mg, Zr, La, and REM, with the balance being iron and the inevitable impurities, directly or after being cooled once and performing the lamination hot in which the lamination finish temperature is 850 to 950 ° C, then cool quickly to 500 to 650 ° C at an average cooling rate of 10 ° C / s or more, and then wind in a coil and cool slowly up to 400 ° C taking 1.0 hour or more;
a cold rolling step of performing cold rolling so that the total reduction ratio is 30 to 75% for pickling subsequent to the hot rolling step;
an annealing step of heating the steel sheet after cold rolling to 750 ° C or more with the average heating rate between 600 and 750 ° C being 20 ° C / s or less, then cooling with the average cooling rate between 750 and 650 ° C with 1.0 to 15.0 ° C / s and cooling with the average rate from 650 ° C with 3.0 ° C / s or more, and run, while holding for 20 to 1000 seconds in the temperature range
Petition 870190015128, of 02/14/2019, p. 6/12
[4]
4/5 from 300 to 470 ° C and while the tension of 5 to 100 MPa is applied in this temperature range, one or more times the bending with a bending radius of 800 mm or less;
a coating step of performing hot dip galvanizing on the steel sheet surfaces to form a coating layer by immersing, after the annealing step, the steel sheet in a galvanizing bath under the conditions of: bath temperature coating: 450 to 470 ° C, temperature of the steel plate at the time of entering the coating bath: 430 to 490 ° C, and effective amount of Al in the coating ring: 0.01 to 0.18% by weight; and a cooling step of cooling at an average cooling rate of 0.5 ° C / s or more to 150 ° C or less after the coating step, where the annealing step is such that in a preheat zone under the condition of an air ratio: 0.7 to 1.2 in a mixed air and combustible gas used in a preheat burner, the air ratio being the ratio of the volume of air contained in the mixed gas in the volume unit and the volume of air logically necessary for the complete combustion of the combustible gas contained in the mixed gas in the volume unit, oxides are generated in a portion of the surface layer of the steel plate by passing during heating to a steel plate temperature of 400 at 800 ° C, then the oxides generated in the preheating zone are reduced by heating to 750 ° C or more in a reduction zone with a partial pressure ratio P (H2Ü) / P (H2) between the steam d ' water (H2O) and hydrogen (H2): 0.0001 to 2.0, and later cooling is performed.
4. Method of production of a hot-dip galvanized steel sheet, characterized by the fact that it consists of:
after the hot rolling step, the rolling step
Petition 870190015128, of 02/14/2019, p. 7/12
[5]
5/5 cold, the annealing step, and the coating step are performed by the method, as defined in claim 3, and before the cooling step, perform a bonding treatment in a coating layer at temperatures from 470 to 620 ° C.

类似技术:

---

公开号 | 公开日 | 专利标题

---

BR112014007545B1|2019-05-14|HIGH-RESISTANT HOT DIP GALVANIZED STEEL SHEET, HIGH-RESISTANT HOT DIP GALVANIZED STEEL SHEET AND METHOD FOR PRODUCTION OF THEM.

---

EP2762583B1|2018-11-07|High-strength hot-dip galvanized steel sheet having excellent delayed fracture resistance and manufacturing method thereof

---

RU2566121C1|2015-10-20|High strength dip galvanized steel plate with excellent characteristic of impact strength, and method of its manufacturing, and high strength alloyed dip galvanized steel plate and method of its manufacturing

---

ES2578952T3|2016-08-03|Cold rolled steel sheet, high strength galvanized steel sheet and high strength alloy hot dipped galvanized steel sheet that has excellent formability and weldability, and methods for manufacturing them

---

RU2573153C2|2016-01-20|High-strength cold rolled steel plate with excellent suitability for flanging-drawing and precision perforation ability, and method of its manufacturing

---

TWI460290B|2014-11-11|Hot rolled steel sheet and producing method thereof

---

BR112014007498B1|2019-04-30|HIGH RESISTANCE HOT GALVANIZED STEEL SHEET AND SAME PRODUCTION METHOD

---

KR20150119072A|2015-10-23|High strength steel plate with excellent delayed destruction resistance characteristics and low temperature toughness, and high strength member manufactured using same

---

BR112014002203B1|2020-10-06|GALVANIZED LAYER, YOUR METHOD FOR PRODUCTION AND STEEL SHEET

---

BR112014001589B1|2019-01-08|high strength steel sheet and high strength galvanized steel sheet excellent in conformability and production methods thereof

---

BRPI0410575B1|2016-07-12|high strength cold rolled steel sheet with tensile strength 780 mpa or more

---

BR112014022007B1|2019-04-30|COLD LAMINATED RESISTANT STEEL SHEET AND METHOD FOR PRODUCTION

---

WO2006106733A1|2006-10-12|High strength cold rolled steel sheet and plated steel sheet excellent in the balance of strength and workability

---

BR112014020244B1|2019-04-30|STEEL PLATE, COATED STEEL PLATE, AND METHOD FOR PRODUCTION OF THE SAME

---

BR112012003763B1|2018-04-17|HOT PRESSED COMPONENT FROM STEEL PLATE, HOT PRESS STEEL PLATE, AND METHOD FOR PRODUCING HOT PRESSED COMPONENT FROM STEEL PLATE

---

CN103108973A|2013-05-15|High-strength hot-rolled steel sheet having superior punchability and method for producing same

---

BRPI0414674B1|2016-11-01|high yield strength and high strength steel sheets and production methods thereof

---

WO2017026125A1|2017-02-16|Material for high-strength steel sheet, hot rolled material for high-strength steel sheet, material annealed after hot rolling and for high-strength steel sheet, high-strength steel sheet, high-strength hot-dip plated steel sheet, high-strength electroplated steel sheet, and manufacturing method for same

---

US20120279617A1|2012-11-08|High strength galvanized steel sheet having excellent fatigue resistance and stretch flangeability and method for manufacturing the same

---

BRPI0822384B1|2020-06-09|hot rolled steel sheet excellent in fatigue properties and stretch flange formability, and method for making it

---

WO2002066697A1|2002-08-29|Thin steel sheet for automobile excellent in notch fatigue strength and method for production thereof

---

BR112014024879B1|2019-01-22|hot-dip galvanized hot-rolled steel sheet and process to produce the same

---

CN106661699B|2018-09-04|High strength hot dip galvanized steel sheet and its manufacturing method

---

BR112014019497B1|2019-04-24|COLD LAMINATED STEEL SHEET, COATED STEEL SHEET, AND METHODS FOR PRODUCING THEM

---

JP5958667B1|2016-08-02|High-strength hot-dip galvanized steel sheet and manufacturing method thereof

同族专利:

---

公开号 | 公开日

---

EP2762585A4|2015-12-02|

---

EP2762585B1|2019-05-29|

---

US9708679B2|2017-07-18|

---

RU2566695C1|2015-10-27|

---

EP2762585B8|2019-07-31|

---

JPWO2013047739A1|2015-03-26|

---

MX357963B|2018-08-01|

---

TWI513524B|2015-12-21|

---

ZA201402355B|2015-01-28|

---

EP2762585A1|2014-08-06|

---

KR20140050750A|2014-04-29|

---

PL2762585T3|2020-01-31|

---

TW201332673A|2013-08-16|

---

ES2737678T3|2020-01-15|

---

CN103874776A|2014-06-18|

---

KR101594268B1|2016-02-15|

---

JP5354135B2|2013-11-27|

---

US20140287263A1|2014-09-25|

---

CA2850332C|2016-06-21|

---

CA2850332A1|2013-04-04|

---

WO2013047739A1|2013-04-04|

---

MX2014003717A|2014-07-09|

---

CN103874776B|2016-05-18|

引用文献:

---

公开号 | 申请日 | 公开日 | 申请人 | 专利标题

---

---

JPS6047886B2|1981-03-02|1985-10-24|Nippon Steel Corp|

---

US4806304A|1983-05-09|1989-02-21|Daido Tokushuko Kabushiki Kaisha|Free cutting steel|

---

JPH0454735B2|1983-05-09|1992-09-01|Daido Steel Co Ltd|

---

JPS6339674B2|1983-05-26|1988-08-05|Nippon Steel Corp|

---

JPS634903B2|1985-07-24|1988-02-01|Nippon Steel Corp|

---

JPH01230715A|1987-06-26|1989-09-14|Nippon Steel Corp|Manufacture of high strength cold rolled steel sheet having superior press formability|

---

US7267890B2|2001-06-06|2007-09-11|Nippon Steel Corporation|High-strength hot-dip galvanized steel sheet and hot-dip galvannealed steel sheet having fatigue resistance corrosion resistance ductility and plating adhesion after servere deformation and a method of producing the same|

---

JP3870891B2|2002-11-05|2007-01-24|Ｊｆｅスチール株式会社|High strength cold-rolled steel sheet|

---

JP4192051B2|2003-08-19|2008-12-03|新日本製鐵株式会社|Manufacturing method and equipment for high-strength galvannealed steel sheet|

---

JP4384523B2|2004-03-09|2009-12-16|新日本製鐵株式会社|Low yield ratio type high-strength cold-rolled steel sheet with excellent shape freezing property and manufacturing method thereof|

---

JP4741376B2|2005-01-31|2011-08-03|新日本製鐵株式会社|High-strength galvannealed steel sheet with good appearance, manufacturing method and manufacturing equipment thereof|

---

ES2441959T3|2006-01-30|2014-02-07|Nippon Steel & Sumitomo Metal Corporation|High strength hot dipped galvanized steel sheet with excellent molding aptitude and plating suitability, and high strength alloy hot dipped galvanized steel sheet, and methods and apparatus for producing them|

---

RU2418094C2|2006-01-30|2011-05-10|Ниппон Стил Корпорейшн|High strength hot-galvanised steel sheet and high strength annealed after galvanising steel sheet with excellent mouldability and ability to application of electro-deposit; procedures and devices for fabrication of such sheets|

---

JP4781836B2|2006-02-08|2011-09-28|新日本製鐵株式会社|Ultra-high strength steel sheet excellent in hydrogen embrittlement resistance, its manufacturing method, manufacturing method of ultra-high strength hot-dip galvanized steel sheet, and manufacturing method of ultra-high-strength galvannealed steel sheet|

---

CA2697226C|2007-10-25|2015-12-15|Jfe Steel Corporation|High tensile strength galvanized steel sheet excellent in formability and method for manufacturing the same|

---

JP5119903B2|2007-12-20|2013-01-16|Ｊｆｅスチール株式会社|Method for producing high-strength hot-dip galvanized steel sheet and high-strength galvannealed steel sheet|

---

JP5369663B2|2008-01-31|2013-12-18|Ｊｆｅスチール株式会社|High-strength hot-dip galvanized steel sheet excellent in workability and manufacturing method thereof|

---

JP5131844B2|2008-08-12|2013-01-30|新日鐵住金株式会社|Hot-rolled steel sheet for hot pressing, manufacturing method thereof, and manufacturing method of hot-pressed steel sheet member|

---

JP4737319B2|2009-06-17|2011-07-27|Ｊｆｅスチール株式会社|High-strength galvannealed steel sheet with excellent workability and fatigue resistance and method for producing the same|

---

JP5499663B2|2009-11-30|2014-05-21|新日鐵住金株式会社|High-strength cold-rolled steel sheet having a maximum tensile strength of 900 MPa or more excellent in mechanical cutting characteristics and its manufacturing method, and high-strength galvanized steel sheet and its manufacturing method|

---

JP5370104B2|2009-11-30|2013-12-18|新日鐵住金株式会社|Manufacturing method of high strength steel plate having high tensile strength of 900 MPa or more excellent in hydrogen embrittlement resistance and high strength cold-rolled steel plate, manufacturing method of high strength galvanized steel plate|

---

JP5434537B2|2009-12-03|2014-03-05|新日鐵住金株式会社|High Si content alloyed hot-dip galvanized steel sheet excellent in weldability and method for producing the same|

---

JP5786318B2|2010-01-22|2015-09-30|Ｊｆｅスチール株式会社|High-strength hot-dip galvanized steel sheet with excellent fatigue characteristics and hole expansibility and method for producing the same|

---

JP2011153349A|2010-01-27|2011-08-11|Sumitomo Metal Ind Ltd|Hot-dip galvannealed steel sheet having excellent appearance characteristic, and method for manufacturing the same|

---

RU2585889C2|2011-09-30|2016-06-10|Ниппон Стил Энд Сумитомо Метал Корпорейшн|High-strength hot-dip galvanised steel sheet having excellent resistance to delayed fracture, and method for production thereof|JP2015034334A|2013-07-12|2015-02-19|株式会社神戸製鋼所|High-strength plated steel sheet excellent in platability, processability and delayed fracture resistance characteristics and production method thereof|

---

JP5799996B2|2013-09-12|2015-10-28|Ｊｆｅスチール株式会社|Hot-dip galvanized steel sheet, alloyed hot-dip galvanized steel sheet excellent in appearance and plating adhesion, and methods for producing them|

---

JP5799997B2|2013-09-12|2015-10-28|Ｊｆｅスチール株式会社|Hot-dip galvanized steel sheet, alloyed hot-dip galvanized steel sheet excellent in appearance and plating adhesion, and methods for producing them|

---

KR101639845B1|2013-12-24|2016-07-14|주식회사 포스코|High strength thick sheet with cutting crack resistance and method for manufacturing the same|

---

JP6306481B2|2014-03-17|2018-04-04|株式会社神戸製鋼所|High-strength cold-rolled steel sheet and high-strength hot-dip galvanized steel sheet excellent in ductility and bendability, and methods for producing them|

---

CN105297033A|2014-05-30|2016-02-03|宝山钢铁股份有限公司|Production method of hot-rolling, pickling-free, direct-cold-rolling and reduction annealing hot-dip product|

---

KR20170027708A|2014-07-07|2017-03-10|타타 스틸 이즈무이덴 베.뷔.|Steel strip having high strength and high formability, the steel strip having a hot dip zinc based coating|

---

EP3170912B1|2014-07-18|2019-05-29|Nippon Steel & Sumitomo Metal Corporation|Steel product and manufacturing method of the same|

---

CN106574319B|2014-08-07|2019-01-01|杰富意钢铁株式会社|High-strength steel sheet and its manufacturing method|

---

US10662496B2|2014-08-07|2020-05-26|Jfe Steel Corporation|High-strength steel sheet and production method for same, and production method for high-strength galvanized steel sheet|

---

CN106574342B|2014-08-07|2018-10-12|杰富意钢铁株式会社|The manufacturing method of high-strength steel sheet and its manufacturing method and high strength galvanized steel plate|

---

JP5983895B2|2014-08-07|2016-09-06|Ｊｆｅスチール株式会社|High strength steel plate and method for producing the same, and method for producing high strength galvanized steel plate|

---

JP6179676B2|2014-10-30|2017-08-16|Ｊｆｅスチール株式会社|High strength steel plate and manufacturing method thereof|

---

WO2016072479A1|2014-11-05|2016-05-12|新日鐵住金株式会社|Hot-dip galvanized steel sheet|

---

EP3216887B1|2014-11-05|2019-10-09|Nippon Steel Corporation|Hot-dip galvanized steel sheet|

---

PL3216892T3|2014-11-05|2019-12-31|Nippon Steel Corporation|Hot-dip galvanized steel sheet|

---

WO2016132549A1|2015-02-20|2016-08-25|新日鐵住金株式会社|Hot-rolled steel sheet|

---

WO2016135898A1|2015-02-25|2016-09-01|新日鐵住金株式会社|Hot-rolled steel sheet or plate|

---

BR112017017443A2|2015-02-25|2018-04-03|Nippon Steel & Sumitomo Metal Corporation|hot rolled steel sheet|

---

EP3284841A4|2015-04-15|2018-12-19|Nippon Steel & Sumitomo Metal Corporation|Hot-rolled steel sheet and method for manufacturing same|

---

US10400320B2|2015-05-15|2019-09-03|Nucor Corporation|Lead free steel and method of manufacturing|

---

RU2684659C1|2015-06-03|2019-04-11|Зальцгиттер Флахшталь Гмбх|Strain-hardening component from galvanized steel, method for its production and method for production of a steel strip suitable for strain hardening of components|

---

KR102014663B1|2015-09-04|2019-08-26|제이에프이 스틸 가부시키가이샤|High strength thin steel sheet and method of producing the same|

---

KR101726090B1|2015-12-22|2017-04-12|주식회사 포스코|High strength galvanized steel sheet having excellent surface property and coating adhesion and method for manufacturing the same|

---

EP3399062B1|2015-12-28|2020-11-04|JFE Steel Corporation|High-strength steel sheet, high-strength galvanized steel sheet, and method for manufacturing same|

---

CN108699664B|2016-02-25|2020-05-12|日本制铁株式会社|High-strength hot-dip galvanized steel sheet having excellent impact peeling resistance and corrosion resistance of worked portion|

---

US11035021B2|2016-03-25|2021-06-15|Nippon Steel Corporation|High-strength steel sheet and high-strength galvanized steel sheet|

---

TWI629367B|2016-08-05|2018-07-11|日商新日鐵住金股份有限公司|Steel plate and plated steel|

---

TWI629369B|2016-08-05|2018-07-11|日商新日鐵住金股份有限公司|Steel plate and plated steel plate|

---

WO2018055425A1|2016-09-22|2018-03-29|Arcelormittal|High strength and high formability steel sheet and manufacturing method|

---

TWI626318B|2016-10-20|2018-06-11|Nippon Steel & Sumitomo Metal Corp|Method for producing plated steel sheet, hot-dip galvanized steel sheet, and method for producing alloyed hot-dip galvanized steel sheet|

---

MX2019007718A|2016-12-26|2019-08-29|Nippon Steel Nisshin Co Ltd|Surface-treated steel plate component having cut end surface, and cutting method therefor.|

---

CN110168125B|2017-02-20|2021-11-26|日本制铁株式会社|High-strength steel plate|

---

WO2018220430A1|2017-06-02|2018-12-06|Arcelormittal|Steel sheet for manufacturing press hardened parts, press hardened part having a combination of high strength and crash ductility, and manufacturing methods thereof|

---

US10953631B2|2017-07-31|2021-03-23|Nippon Steel Corporation|Hot-dip galvanized steel sheet|

---

JP6281671B1|2017-07-31|2018-02-21|新日鐵住金株式会社|Hot-dip galvanized steel sheet|

---

CN110959047B|2017-07-31|2022-01-04|日本制铁株式会社|Hot-dip galvanized steel sheet|

---

CN107699791B|2017-09-28|2019-05-03|邯郸钢铁集团有限责任公司|900MPa grades high cold-bending property low alloy high strength steel plate and preparation method thereof|

---

CN107604266A|2017-10-31|2018-01-19|桂林加宏汽车修理有限公司|A kind of toughness steel alloy|

---

CN111295459A|2017-11-14|2020-06-16|日本制铁株式会社|Method for manufacturing alloyed hot-dip galvanized steel sheet|

---

JP6901417B2|2018-02-21|2021-07-14|株式会社神戸製鋼所|High-strength steel sheet and high-strength galvanized steel sheet, and their manufacturing method|

---

CN108441763B|2018-03-23|2019-11-19|马钢控股有限公司|A kind of tensile strength 1000MPa grades of cold rollings galvanizing by dipping high-strength steel and preparation method thereof|

---

TWI651418B|2018-03-30|2019-02-21|日商新日鐵住金股份有限公司|Alloyed hot-dip galvanized steel sheet|

---

JP6697728B1|2018-10-04|2020-05-27|日本製鉄株式会社|Cold rolled steel sheet|

---

CN109371325A|2018-11-30|2019-02-22|宝山钢铁股份有限公司|A kind of electrogalvanized thermoforming steel plate that cold-bending property is excellent or steel band and its manufacturing method|

---

JP6787522B1|2019-01-30|2020-11-18|Ｊｆｅスチール株式会社|High-strength steel sheet and its manufacturing method|

---

US20220064771A1|2019-02-06|2022-03-03|Nippon Steel Corporation|Hot dip galvanized steel sheet and method for producing same|

---

EP3960892A1|2019-04-24|2022-03-02|Nippon Steel Corporation|Steel sheet|

---

TWI697563B|2019-09-26|2020-07-01|中國鋼鐵股份有限公司|Billet reheating furnace and method for inhibiting thickening of surface decarburization layer of billet|

---

CN111850262A|2020-06-22|2020-10-30|鞍钢蒂森克虏伯汽车钢有限公司|Production method of ultra-low carbon baking hardening continuous hot-dip galvanized steel sheet|

---

CN111850263A|2020-06-22|2020-10-30|鞍钢蒂森克虏伯汽车钢有限公司|Production method for improving aging resistance of continuous hot-dip galvanizing baking hardened steel plate|

---

CN113186459A|2021-04-08|2021-07-30|山东钢铁股份有限公司|Cold-rolled low-alloy steel strip with yield strength of 355MPa and preparation method thereof|

法律状态:
2018-05-08| B07A| Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]|

---

2018-12-11| B06A| Patent application procedure suspended [chapter 6.1 patent gazette]|

---

2018-12-18| B06A| Patent application procedure suspended [chapter 6.1 patent gazette]|

---

2019-01-15| B06I| Publication of requirement cancelled [chapter 6.9 patent gazette]|Free format text: ANULADA A PUBLICACAO CODIGO 6.1 NA RPI NO 2502 DE 18/12/2018 POR TER SIDO INDEVIDA. |

---

2019-03-12| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

---

2019-05-14| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 28/09/2012, OBSERVADAS AS CONDICOES LEGAIS. (CO) 20 (VINTE) ANOS CONTADOS A PARTIR DE 28/09/2012, OBSERVADAS AS CONDICOES LEGAIS |

---

2019-11-26| B25D| Requested change of name of applicant approved|Owner name: NIPPON STEEL CORPORATION (JP) |

---

2021-08-10| B21F| Lapse acc. art. 78, item iv - on non-payment of the annual fees in time|Free format text: REFERENTE A 9A ANUIDADE. |

---

2021-11-30| B24J| Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)|Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2640 DE 10-08-2021 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |

优先权:

---

申请号 | 申请日 | 专利标题

---

JP2011218773|2011-09-30|

---

JP2011-218773|2011-09-30|

---

PCT/JP2012/075061|WO2013047739A1|2011-09-30|2012-09-28|High-strength hot-dip galvanized steel sheet with excellent mechanical cutting characteristics, high-strength alloyed hot-dip galvanized steel sheet, and method for producing said sheets|

---